Q. No.
Match the reaction given in Column I with the corresponding name of the reaction given in Column II.
| Column-I | Column-II | ||
| (a) | C6H5CHO + NaOH ⟶ C6H5COOH + C6H5CH2OH | (i) | Rosenmund reduction |
| (b) | \(\small(C_{6}H_{6} \ + \ CH_{3}Cl \ \xrightarrow[]{Anhyd.AlCl_{3}} C_{6}H_{5}CH_{3}\) | (ii) | Kolbe's reaction |
| (c) | \(\mathrm{RCOCl}+\mathrm{H}_2 \ \xrightarrow[]{Pd/BaSO_{4}} \ \text { RCHO }\) | (iii) | Claisen reaction |
| (d) | C6H5OH + NaOH + CO2 \(\xrightarrow[2. \ H^{+}]{1. \ Heat}\) Salicylic acid | (iv) | Cannizzaro reaction |
| (v) | Friedel-Craft's reaction | ||
The correct match is:
| Options: | (a) | (b) | (c) | (d) |
| 1. | iv | v | i | ii |
| 2. | v | i | ii | iii |
| 3. | v | iii | ii | i |
| 4. | iv | ii | iii | i- |
The most reactive compound among the following toward nucleophilic addition reaction is:
| 1. |  |
2. |  |
| 3. |  |
4. |  |
In the above reaction, the structure of ‘A’ and the type of isomerism shown in the final product are, respectively,:
| 1. | Prop-1-en-2-ol and Metamerism |
| 2. | Prop-1-en-1-ol and Tautomerism |
| 3. | Prop-2-en-2-ol and Geometrical isomerism |
| 4. | Prop-1-en-2-ol and Tautomerism |
Match the acids given in Column I with their correct IUPAC names given in Column II and mark the appropriate option.
| Column I (Acids) |
Column I (IUPAC names) |
||
| (i) | Phthalic acid | (a) | Hexane-1,6-dioic acid |
| (ii) | Oxalic acid | (b) | Benzene-1,2-dicarboxylic acid |
| (iii) | Succinic acid | (c) | Pentane-1,5-dioic acid |
| (iv) | Adipic acid | (d) | Butane-1,4-dioic acid |
| (v) | Glutaric acid | (e) | Ethane-1,2-dioic acid |
1. (i) — (a), (ii) — (b), (iii) — (c), (iv) — (d), (v) — (e)
2. (i) — (b), (ii) — (e), (iii) — (d), (iv) — (a), (v) — (c)
3. (i) — (b), (ii) — (a), (iii) — (d), (iv) — (e), (v) — (c)
4. (i) — (a), (ii) — (e), (iii) — (c), (iv) — (b), (v) — (d)
An acid that forms an anhydride (X) on heating and an acid imide (Y) on strong heating with ammonia is:
| 1. |  |
2. |  |
| 3. |  |
4. |  |
The reactant 'A' in the below-mentioned reaction is:
| 1. | Benzoyl chloride | 2. | Toluene |
| 3. | Acetophenone | 4. | Benzoic acid |
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