The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol–1. The dissociation constant of acetic acid is :

(\(\mathrm{\Lambda_{H^{+}}^{o} \ = \ 350 \ S \ cm^{2} \ mol^{-1} }\))
(\(\mathrm{\mathrm{\Lambda_{CH_{3}COO^{-}}^{o} \ = \ 50 \ S \ cm^{2} \ mol^{-1} }}\))

1. 1.75×10-5 mol L–1 

2. 2.50×10-5 mol L–1 

3. 1.75×10-4 mol L–1 

4. 2.50×10-4 mol L–1 

Subtopic:   Kohlrausch Law & Cell Constant |
 62%
Level 2: 60%+
NEET - 2021
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At 25ºC, molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is \(\mathrm{9.54 ~ohm^{–1}cm^2 mol^{–1}}\) and at infinite dilution, its molar conductance is \(\mathrm{238 ~ohm^{–1} cm^2~ mol^{–1}.}\) The degree of ionization of ammonium hydroxide at the same concentration and temperature is:
1. 20.800%
2. 4.008%
3. 40.800%
4. 2.080%
Subtopic:   Kohlrausch Law & Cell Constant |
 82%
Level 1: 80%+
AIPMT - 2013
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Molar conductivities (∧°m) at infinite dilution of
NaCl, HCl, and CH3COONa are 126.4, 425.9, and 91.0 S cm2 mol–1 respectively.
 (∧°m)  for CH3COOH  will be: 

1. \(180.5~S~cm^2~mol^{-1}\) 2. \(290.8~S~cm^2~mol^{-1}\)
3. \(390.5~S~cm^2~mol^{-1}\) 4. \(425.5~S~cm^2~mol^{-1}\)
Subtopic:   Kohlrausch Law & Cell Constant |
 91%
Level 1: 80%+
AIPMT - 2012
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The variation of molar conductivity with the concentration of an electrolyte (X) in an aqueous solution is shown in the given figure.

The electrolyte X is:

1. CH3COOH 2. KNO3
3. HCl 4. NaCl
Subtopic:   Kohlrausch Law & Cell Constant |
 92%
Level 1: 80%+
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The correct statement(s) among the following is/are:
 
A. Kohlrausch's law of independent migration of ions is applicable for strong electrolytes only.
B.  At equilibrium state, \(E_{cell}^{o}\) = 0.
C. For the spontaneous cell reaction, Ecell > 0 and \(\Delta_rG < 0 \).
 
1. Only A  2. B and C
3. Only C 4. A, B and C
Subtopic:   Kohlrausch Law & Cell Constant |
Level 3: 35%-60%
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