The type of isomerism shown by the complex [CoCl2(en)2]+ is:
1. Geometrical isomerism
2. Coordination isomerism
3. Ionization isomerism
4. Linkage isomerism
Subtopic:  Isomerism in Coordination Compounds |
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Iron carbonyl, FeCO5 is:

1. Tetranuclear

2. Mononuclear

3. Trinuclear

4. Dinuclear

Subtopic:  Organometallic Complexes & their Uses |
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The geometry and magnetic behaviour of the complex [Ni(CO)4] respectively are:

1. Square planar and diamagnetic

2. Tetrahedral and diamagnetic

3. Square planar and paramagnetic

4. Tetrahedral and paramagnetic

Subtopic:  VBT, CFT & their Limitations |
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An example of a sigma bonded organometallic compound is:

1. Ruthenocene                 

2. Grignard's reagent

3. Ferrocene                     

4. Cobaltocene

Subtopic:  Ligands | VBT, CFT & their Limitations |
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The correct order of the stoichiometrics of AgCl formed when AgNO3 in excess is treated with the complexes:- CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3, respectively, is :

1. 1 AgCl, 3 AgCl, 2 AgCl

2. 3 AgCl, 1 AgCl, 2 AgCl

3. 3 AgCl, 2 AgCl, 1 AgCl

4. 2 AgCl, 3AgCl,  1 AgCl

Subtopic:  Werner’s Theory |
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An example of a sigma bonded organometallic compound is:

1. Grignard's reagent

2. Ferrocene

3. Cobaltocene

4. Ruthenocene

Subtopic:  Organometallic Complexes & their Uses |
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What is the correct increasing order for the wavelengths of absorption in complexes of Co3+?

1. [Co(H2O)6]3+ < [Co(en)3]3+ < [Co(NH3)6]3 +

2. [Co(H2O)6]3+ <  [Co(NH3)6]3+ <  [Co(en)3]3+

3. [Co(NH3)6]3+ < [Co(en)3]3+ < [Co(H2O)6]3+

4. [Co(en)3]3+ <  [Co(NH3)6]3+ < [Co(H2O)6]3+

Subtopic:  VBT, CFT & their Limitations |
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Pick out the correct statement with respect to [Mn(CN)6]3-

1. It is sp3d2 hybridised and tetrahedral

2. It is d2sp3 hybridised and octahedral

3. It is dsp2 hybridised and square planar

4. It is sp3d2 hybridised and octahedral

Subtopic:  VBT, CFT & their Limitations |
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The correct increasing order of trans-effect of the following species is

1. NH3 > CN- > Br- > C6H5-

2. CN- > C6H5- > Br- > NH3

3. Br- > CN- >NH> C6H5-

4. CN- > Br- >C6H5- >NH3

 

 

Subtopic:  VBT, CFT & their Limitations |
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Jahn-Teller effect is not observed in high spin complexes of

1. d7

2. d8

3. d4

4. d9

Subtopic:  VBT, CFT & their Limitations |
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