Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called    

1. Clemmenson reduction

2. Cope reduction

3. Dow reduction

4. Wolff-Kishner reduction

Aldol condensation will not take place in

1. HCHO 

2. ${\mathrm{CH}}_3\mathrm{CHO}$

3. ${\mathrm{CH}}_3{\mathrm{COCH}}_3$

4. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{CHO}$

Which one of the following on oxidation gives a ketone?                       

1. primary alcohol                     

2. secondary alcohol

3. tertiary alcohol                     

4. All of these

 A and B in the following reactions are $\underset{\mathrm{KCN}}{\overset{\mathrm{HCN}/}{\to }}$A$\stackrel{\mathrm{B}}{\to }$         

1. A=${\mathrm{RR}}^{\text{'}}{\mathrm{CH}}_2\mathrm{CN}$, B=NaOH

2. A=, B=${\mathrm{CH}}_3$

3. A=, B=${\mathrm{CH}}_3$

4. A=, B=${\mathrm{LiAlH}}_4$

 

1.
2.
3.
4.	​​​​​​​

Consider the following reaction,

Phenol$\stackrel{\mathrm{Zn}-\mathrm{dust}}{\to }$X$\underset{\mathrm{Anhy}.{\mathrm{AlCl}}_3}{\overset{{\mathrm{CH}}_3\mathrm{Cl}}{\to }}$Y$\stackrel{\mathrm{Alk}.{\mathrm{KMnO}}_4}{\to }$Z 

The product Z is                            

1. toluene

2. benzaldehyde

3. benzoic acid

4. benzene

Benzoic acid gives benzene on being heated with X and phenol gives benzene on being heated with Y. Therefore, X and Y are respectively                                                              

1. Sodalime and copper

2. Zn dust and NaOH

3. Cu and sodalime

4. Sodalime and zinc dust

The product formed in aldol condensation is                                                                 

1. a beta-hydroxy acid

2. a beta-hydroxy aldehyde or a beta-hydroxy ketone

3. an alpha-hydroxy aldehyde or ketone

4. an alpha, beta unsaturated ester

Consider the following transformations

CH₃COOH $\stackrel{{\mathrm{CaCO}}_3}{\to }$A$\stackrel{\mathrm{heat}}{\to }$B$\underset{\mathrm{NaOH}}{\overset{{\mathrm{I}}_2}{\to }}$C The molecular formula of C is                       

1. ${\mathrm{CH}}_3-\underset{\mathrm{I}}{\overset{\mathrm{OH}}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_3$

2. ${\mathrm{ICH}}_2-{\mathrm{COCH}}_3$

3. ${\mathrm{CHI}}_3$

4. ${\mathrm{CH}}_3\mathrm{I}$

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of $\mathrm{\alpha }$-hydroxy acid. The carbonyl compound is

1. acetaldehyde 

2. acetone

3. diethyl ketone 

4. formaldehyde