Consider the following ionisation reactions :
I.E. (kJ )
If monovalent positive ion of A, divalent positive ion of B and trivalent positive ion of C have zero electron. Then incorrect order of corresponding I.E. is :
(1)
(2)
(3)
(4)
Find the incorrect match among the following electronic configurations and their corresponding period and group numbers.
1. [Ar] 3d⁵ 4s¹ → 4th period, 6th group Which of the following orders is correct for the property mentioned in brackets?
1.S²⁻ > Cl⁻ > K⁺ > Ca²⁺ (Ionisation energy)
2. C < N < F < O (Second ionisation energy)
3. B > Al > Ga > In > Tl (Electronegativity)
4. Na⁺ > Li⁺ > Mg²⁺ > Be²⁺ > Al³⁺ (Ionic radius)
and for Mg are 178 Kcal mol–1 and 348 Kcal , respectively. The energy required for the reaction, will be:
1. +170 Kcal
2. +526 Kcal
3. –170 Kcal
4. –526 Kcal
Incorrect statement about characteristics regarding halogens is :
1. Ionization energy decreases with increase in atomic number.
2. Electronegativity decreases with increase in atomic number.
3. Electron affinity decreases with increase in atomic number.
4. Enthalpy of fusion increases with increase in atomic number.
Consider the following statements:
| (I) | Rutherford name was associated with the development of periodic table. |
| (II) | A metal M having electronic configuration \(1 s^2, 2 s^2, 2 p^6, 3 s^2, 3 p^6, 3 d^{10}, 4 s^1\) is d-block element. |
| (III) | Diamond is an element. |
| (IV) |
The electronic configuration of the most electronegative elements is\(1 s^2, 2 s^2, 2 p^5\) |
Choose the correct option from the given codes.
| 1. | I, II, IV | 2. | I, II, III, IV |
| 3. | II, IV | 4. | I, III, IV |
There are four elements 'p', 'q', 'r' and 's' having atomic number Z-1, Z, Z+1 and Z+2 respectively. If there element 'q' is an inert gas, select the correct answers from the following statements.
(i) 'p' has most negative electron gain enthalpy in the respective period.
(ii) 'r' is an alkali metal.
(iii) 's' exists in +2 oxidation state.
(1) (i) and (ii)
(2) (ii) and (iii)
(3) (i) and (iii)
(4) (i), (ii) and (iii)
Which of the following orders are correct for the ionization energies?
(A) \( B a < S r < C a \)
(B) \(S^{2 -} < S < S^{2 +}\)
(C) \(C < O < N\)
(D) \(M g < A l < S i\)
1. A, B and D
2. A, C and D
3. A, B and C
4. A, B, C and D
The electron gain enthalpies of halogens in kJ mol-1 are given below.
F =-332, Cl =-349, Br =-325, I =-295.
The lesser negative value for F as compared to that of Cl is due to:
| 1. | Strong electron-electron repulsions in the compact 2p-subshell of F |
| 2. | Weak electron-electron repulsions in the bigger 3p-subshell of Cl |
| 3. | Smaller electronegativity value of F than Cl |
| 4. | 1 & 2 both |
Which of the following statements are correct ?
| (i) | Generally the radius trend and the ionization energy trend across a period are exact opposites. |
| (ii) | Electron affinity values of elements may be exothermic (negative) or endothermic (positive). |
| (iii) | The first ionization energy of sulphur is higher than that of phosphorus. |
| (iv) | \(Te^{2-} > I^- > Cs^+ > Ba^{2+}\) represents the correct decreasing order of ionic radii. |
1. (i), (iii) and (iv)
2. (ii), (iii) and (iv)
3. (i), (ii) and (iv)
4. (i), (ii) and (iii)