Which of the following resonating structures of 1-methoxy-1,3-butadiene is least stable?

1. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
2. \(C H_2=\mathrm{CH}_2-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
3. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\mathrm{CH}-\mathrm{O}-\mathrm{CH}_3\)
4. \(\mathrm{CH}_2=\mathrm{CH}-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{O}-\mathrm{CH}_3\)

Subtopic:  Electron Displacement Effects |
Level 3: 35%-60%
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The least stable resonance structure among the following is:

1. 2.
3. 4.

Subtopic:  Electron Displacement Effects |
Level 3: 35%-60%
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Hyperconjugation involves the overlap of the following orbitals:

1. σ - σ

2. σ - p

3. p - p

4. π - π

Subtopic:  Electron Displacement Effects |
 65%
Level 2: 60%+
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The IUPAC name of the compound shown below is:

1. 2-bromo-6-chlorocyclohex-1-ene

2. 6-bromo-6-chlorocyclohexene

3. 3-bromo-1-chlorocyclohex-1-ene

4. 1-bromo-3-chlorocyclohexene

Subtopic:  Nomenclature |
 89%
Level 1: 80%+
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Which of the following structures are superimposable?

(1) 

(2) 

(3) 

(4) 

(1) 1 and 2

(2) 2 and 3

(3) 1 and 4

(4) 1 and 3

 

 

 

 

 

Subtopic:  Stereo Isomers |
Level 3: 35%-60%
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The production of an optically active compound from a symmetric molecule without resolution in termed as:

(1) Walden inversion

(2) partial racemisation

(3) asymmetric synthesis

(4) partial resolution

Subtopic:  Stereo Isomers |
Level 3: 35%-60%
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Find the type of isomerism shown by buta-1,3-diene and but-2-yne.

1. Position isomers

2. Functional isomers

3. Chain isomers

4. Tautomers

Subtopic:  Structural Isomers |
 77%
Level 2: 60%+
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Find the number of different substitution products possible when ethane reacts with chlorine
in the presence of sunlight.
 

1. Nine (9)
2. Six (6)
3. Eight (8)
4. Five (5)
Subtopic:  Structural Isomers |
Level 3: 35%-60%
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In butane, which of the following forms has the lowest energy?

(1) Gauche form

(2) Eclipsed form

(3) Staggered form

(4) None of these

Subtopic:  Conformational Isomers |
 67%
Level 2: 60%+
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What is the relationship between the two given molecular structures?

1. Enantiomers 2. Position isomers
3. Conformers 4. None of the above
Subtopic:  Conformational Isomers |
 66%
Level 2: 60%+
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