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Which of the following compounds undergoes nucleophilic substitution reaction most easily?

1. 2.
3. 4.

Subtopic:  Mechanism of Reactions |
 79%
Level 2: 60%+
AIPMT - 2011
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Consider the reactions:

(i) \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5OH}{(CH_3)}_2CHCH_2OC_2H_5 + HBr}\)    
(ii) \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5O^-}{(CH_3)}_2CHCH_2OC_2H_5 + Br^-}\)    

The mechanisms of reactions (i) and (ii) are, respectively:
1. SN2 and SN1
2. SN1 and SN2
3. SN1 and SN1
4. SN2 and SN2
Subtopic:  Mechanism of Reactions |
 53%
Level 3: 35%-60%
AIPMT - 2011
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\(C_6H_5CH_2Br \xrightarrow[2.~H_3O^+] {1.Mg,Ether}~\mathrm X, \)
The product 'X' in the above reaction is:
1. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OH} \)
2. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_3 \)
3. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{C}_6 \mathrm{H}_5 \)
4. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OCH}_2 \mathrm{C}_6 \mathrm{H}_5\)

Subtopic:  Chemical Properties |
 61%
Level 2: 60%+
AIPMT - 2010
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Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?

1. Ethyl chloride

2. Isopropyl chloride

3. Benzyl chloride

4. Chlorobenzene

Subtopic:  Mechanism of Reactions |
 54%
Level 3: 35%-60%
AIPMT - 2005
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The –OH group of an alcohol or the carboxylic acid can be replaced by – Cl using: 

1. Hypochlorous acid 2. Chlorine
3. Hydrochloric acid 4. Phosphorous pentachloride
Subtopic:  Chemical Properties |
 73%
Level 2: 60%+
AIPMT - 2004
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Given below is a reaction sequence:
\(\begin{aligned} & CH_3CH_2Cl\xrightarrow{NaCN}X\xrightarrow{H_2/Ni}Y\\ &Y\xrightarrow{\text{Acetic Anhydride}}Z \end{aligned}\)

Z in the above reaction is:

1. CH3CH2CH2NHCOCH3

2. CH3CH2CH2NH2

3. CH3CH2CH2CONHCH3

4. CH3CH2CH2CONHCOCH3

Subtopic:  Chemical Properties |
 73%
Level 2: 60%+
AIPMT - 2002
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obtained by chlorination of n-butane, will be:
1.  Meso form
2.  Racemic mixture
3.  d-form
4.  l-form

Subtopic:  Isomerism & Chirality |
 85%
Level 1: 80%+
AIPMT - 2001
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An organic compound A(C4H9Cl) in reaction with Na/diethyl ether gives a hydrocarbon which on monochlorination gives only one chloro derivative. A is:

1. t-butyl chloride
2. sec. butyl chloride
3. Iso butyl chloride
4. n-butyl chloride

Subtopic:  Chemical Properties |
 70%
Level 2: 60%+
AIPMT - 2001
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A compound that does not undergo SN1 reaction with OH- is:

1. 2.
3. 4.
 

Subtopic:  Chemical Properties |
 52%
Level 3: 35%-60%
NEET - 2020
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Find the correct sequence of the bond enthalpy of the "C-X" bond among the following:

1. CH3-F < CH3-Cl > CH3-Br > CH3-I

2. CH3-Cl > CH3-F > CH3-Br > CH3-I

3. CH3-F < CH3-Cl < CH3-Br < CH3-I

4. CH3-F > CH3-Cl > CH3-Br > CH3-I

Subtopic:  Introduction and Physical Properties | Chemical Properties |
 64%
Level 2: 60%+
NEET - 2021
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