Among the following reactions, the incomplete combustion of methane is:
1. | \(2 {CH}_4+{O}_2 \xrightarrow[]{\mathrm{Cu/523 \ K/100 \ atm}} 2 {CH}_3 {OH}\) |
2. | \({CH}_4+{O}_2 \xrightarrow[]{{Mo_{2}O_{3}}} {HCHO}+{H}_2 {O}\) |
3. | \(CH_4 + O_2 → C + 2H_2O\) |
4. | \(CH_4 + 2O_2 → CO_2 + 2H_2O\) |
Arrange the following alkyl halides in decreasing order of the rate of -elimination reaction with alcoholic KOH.
A. | |
B. | CH3-CH2-Br |
C. | CH3-CH2-CH2-Br |
1. A > B > C
2. C > B > A
3. B > C > A
4. A > C > B
Which of the following is a free radical substitution reaction?
1. Benzene with Br2/AlCl3
2. Acetylene with HBr
3. Methane with Br2/hv
4. Propene with HBr/(C6H5COO)2
Match the reagent from Column I which on reaction with CH3-CH=CH2 gives the same product given in Column II as per the codes given below
Column I | Column II | ||
A. | O3/Zn+H2O | 1. | Acetic acid and CO2 |
B. | KMnO4/H+ | 2. | Propan-1-ol |
C. | dil. KMnO4/OH- | 3. | Propane-1,2-diol |
D. | B2H6/NaOH+ and H2O2 | 4. | Acetaldehyde and formaldehyde |
Codes:
Options: | A | B | C | D |
1. | 4 | 1 | 3 | 2 |
2. | 1 | 2 | 3 | 4 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 1 | 2 | 3 |
The correct order of decreasing reactivity of the following compounds:
Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene
with an electrophile (E+) is :
1. | Chlorobenzene > p–Nitrochlorobenzene > 2,4-Dinitrochlorobenzene |
2. | p – Nitro chlorobenzene > 2, 4-Dinitrochlorobenzene > Chlorobenzene |
3. | Chlorobenzene > 2, 4-Dinitrochlorobenzene > p-Nitrochlorobenzene |
4. | 2, 4-Dinitrochlorobenzene > Chlorobenzene > p-Nitrochlorobenzene |
Decreasing order of acidic behavior of benzene, n-hexane, and ethyne is:
1. Hexane > Ethyne > Benzene
2. Benzene > Hexane > Ethyne
3. Ethyne > Benzene > Hexane
4. Benzene > Ethyne > Hexene
The products formed after ozonolysis of Pent-2-ene are:
1. | Ethanal and Methanal | 2. | Ethanal and Propanal |
3. | Ethanal and Butanal | 4. | Ethanal and Ethanol |
Mark the correct order of reactivity towards the electrophilic aromatic substitution reaction.
1. | I > II > III > IV | 2. | IV > III > II > I |
3. | II > I > IV > III | 4. | II > I > III > IV |
Which of the following is/are aromatic structure(s)?
a. | ![]() |
b. | ![]() |
c. | ![]() |
d. | ![]() |
1. | a and b | 2. | b and c |
3. | c and d | 4. | a and c |
The dihedral angle of the least stable conformer of ethane is:
1. | 60° | 2. | 0° |
3. | 120° | 4. | 180° |