The effect of a catalyst in a chemical reaction is
to change the
1. Acivation energy
2. Equilibrium concentration
3. Heat of reaction
4. Final products
The plot of log k vs helps to calculate :
1. Energy of activation.
2. Rate constant of reaction.
3. Order of the reaction.
4. Energy of activation as well as the frequency factor.
| 1. | \( 1600 \text { K }\) | 2. | \(1200 \times 4.606 \mathrm{~K}\) |
| 3. | \(\dfrac{1200}{4.606} \mathrm{~K}\) | 4. | \(\dfrac{600}{4.606} K\) |
A hydrogenation reaction is carried out at 500 K. When the same reaction is carried out in the presence of a catalyst, it proceeds at the same rate with the same frequency factor at 400 K.
The catalyst lowers the activation energy by 16 kJ mol⁻¹.
What is the activation energy of the uncatalyzed reaction (in kJ mol⁻¹)?
1. 100 kJ/mol
2. 80 kJ/mol
3. 60 kJ/mol
4. None of the above

1. 0.288
2. 0.577
3. 1.154
4. None of these
The gaseous decomposition reaction, A(g) 2B(g) + C(g) is observed to first order over the excess of liquid water at It is found that after 10 minutes the total pressure of the system is 188 torr and after a very long time, it is 388 torr. The rate constant of the reaction is :
[Given : vapour pressure of at is 28 torr (In 2 = 0.7, In 3 = 1.1, In 10 = 2.3)]
1. 0.02
2. 1.2
3. 0.2
4. None of these