The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 oC is:
1. 10.52 cal/(mol K)
2. 21.04 cal/(mol K)
3. 5.260 cal/(mol K)
4. 0.526 cal/(mol K)
Given the following reaction:
\(4H(g)\)→ \(2 H_{2}\)\((g)\)
The enthalpy change for the reaction is -869.6 kJ. The dissociation energy of the H-H bond is:
1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ
Standard entropies of X2, Y2 and XY3 are 60, 40 and 50JK-1mol-1 respectively. For the reaction
to be at equilibrium, the temperature should be:
1. 750 K
2. 1000 K
3. 1250 K
4. 500 K
From the following bond energies:
H—H bond energy: 431.37 kJ mol-1
C=C bond energy: 606.10 kJ mol-1
C—C bond energy: 336.49 kJ mol-1
C—H bond energy: 410.50 kJ mol-1
Enthalpy for the reaction,
will be:
1. | 1523.6 kJ mol-1 | 2. | -243.6 kJ mol-1 |
3. | -120.0 kJ mol-1 | 4. | 553.0 kJ mol-1 |
The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g)
This reaction will be spontaneous at:
1. 710 K
2. 910 K
3. 1110 K
4. 510 K
1. ΔH = 0 and ΔS < 0
2. ΔH > 0 and ΔS > 0
3. ΔH < 0 and ΔS < 0
4. ΔH > 0 and ΔS < 0
1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V
1. 93 kJ mol-1
2. - 245 kJ mol-1
3. -93 kJ mol-1
4. 245 kJ mol-1
The bond energy of H—H and Cl-Cl is 430 kJ mol-1 and 240 kJ mol-1 respectively
and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:
1. 290
2. 380
3. 425
4. 245
1. | Carbon and hydrogen act as suitable reducing agents for metal sulphides |
2. | The \(\Delta_f G^0\) of the sulphide is greater than those for \(C S_2\) and \(\mathrm{H}_2 \mathrm{~S}\) |
3. | The \(\Delta_f G^0\) is negative for roasting of sulphur ore to oxide. |
4. | Roasting of the sulphide to the oxide is thermodynamically feasible |