Propene, CH₃-CH=CH₂ can be converted into 1-propanol by oxidation. Which set of reagents among the following is ideal to effect the conversion?

1. Alkaline KMnO₄

2. B₂H₆ and alk. H₂O₂

3. O₃/zinc dust

4. OsO₄/CHCl₃

Identify Z in the sequence:
\(\mathrm{CH}_ 3-\mathrm{CH}_2-\mathrm{CH}=\mathrm{CH}_2 \xrightarrow{\mathrm{HBr} / \mathrm{H}_2 \mathrm{O}_2} \mathrm{Y} \xrightarrow{\mathrm{C}_2 \mathrm{H}_5 \mathrm{O}^{-}\mathrm{Na}^{+}} \mathrm{Z} \)

1.
2.
3.	\( \mathrm{CH}_3-\left(\mathrm{CH}_2\right)_3-\mathrm{O}-\mathrm{CH}_2-\mathrm{CH}_3 \)
4.	\( \mathrm{CH}_3-\left(\mathrm{CH}_2\right)_4-\mathrm{O}-\mathrm{CH}_3 \)

An alkene, obtained by the dehydration of an alcohol(A), on ozonolysis gives two molecules of acetaldehyde for every molecule of alkene. the alcohol (A) is:

1. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2\mathrm{OH}$

2. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{OH}$

3. ${\mathrm{CH}}_3\mathrm{CH}={\mathrm{CHCH}}_2\mathrm{OH}$

4. ${\mathrm{CH}}_3{\mathrm{CH}}_2\underset{\mathrm{OH}}{\underset{\mathrm{I}}{\mathrm{CH}}}{\mathrm{CH}}_3$

Propene on reaction with diazomethane in presence of UV radiations gives:

(1) cyclopropane

(2) methyl cyclopropane

(3) butane

(4) butene

Identify Z in the following series,

${\mathrm{CH}}_2={\mathrm{CH}}_2<mspace\; width="1em"></mspace>\stackrel{\mathrm{HBr}}{\to }<mspace\; width="1em"></mspace>X<mspace\; width="1em"></mspace>\stackrel{\mathrm{Hydrolysis}}{\to }<mspace\; width="1em"></mspace>Y<mspace\; width="1em"></mspace>\underset{{\mathrm{I}}_2<mspace\; width="1em"></mspace>\mathrm{excess}}{\overset{{\mathrm{Na}}_2{\mathrm{CO}}_3}{\to }}<mspace\; width="1em"></mspace>Z<mspace\; width="1em"></mspace>:$

1. ${\mathrm{C}}_2{\mathrm{H}}_5\mathrm{I}$

2. ${\mathrm{C}}_2{\mathrm{H}}_5\mathrm{OH}$

3. ${\mathrm{CHI}}_3$

4. ${\mathrm{CH}}_3\mathrm{CHO}$

CH₃CH=CHCHO is oxidized to CH₃CH=CHCOOH using:

1. Alkaline permanganate

2. Ammoniacal silver nitrate

3. Selenium dioxide

4. Osmium tetroxide

$\mathrm{R}-\mathrm{COOH}$$\to \hspace{0.17em}$RCH₂OH. This mode of reduction can be effected only by:

1. NaBH₄

2. KMnO₄

3. LiAIH₄

4. All of the above

Acetylene can be converted to higher alkyne using the following sequence of reactions:

(1) Na,RX

(2) RMg X,R X

(3) either of these two

(4) none of these

The product formed during the reaction,

$\mathrm{CH}\equiv \mathrm{CH}+\mathrm{NaOCl}\stackrel{0°\mathrm{C}}{\to }\mathrm{is}:$
$$

1. 1,2-Dichloroethane

2. 1,1-Dichloroethane

3. 1,2-Dichloroethene

4. 1,2-Dichloroethyne