Ethylene diaminetetraacetate (EDTA) ion is:

1. Bidentate ligand with two "N" donor atoms
2. Tridentate ligand with three "N" donor atoms
3. Hexadentate ligand with four "O" and two "N'' donor atoms
4. Unidentate ligand

Subtopic:  Ligands |
 83%
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Match Column I with Column II, Columns I and II represent complexes and magnetic moment (BM) respectively. 

Column I Column II
(a). [FeCN6]3- (i). 5.92 BM
(b). [Fe(H2O)6]3+ (ii). 0 BM
(c). [Fe(CN)6]4- (iii). 4.90 BM
(d). [Fe(H2O)6]2+ (iv). 1.73 BM

Choose the correct answer from the options given below:

(a). (b). (c). (d).
1. (i). (iii). (iv). (ii).
2. (iv). (i). (ii). (iii).
3. (iv). (ii). (i). (iii).
4. (ii). (iv). (iii). (i).
Subtopic:  VBT, CFT & their Limitations |
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The correct statement(s) among the following options is/are :

1. Complexes in which the metal ion is bound to only one kind of a donor group are homoleptic complexes.

2. Heteroleptic complexes are those complexes where the central metal ion is bound to only one type of donor group.

3. [Pt(Cl)4]2- is an example of a homoleptic complex.

4. Both (1) and (3) 

Subtopic:  Introduction, Classification and Nomenclature |
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The incorrect statement(s) among the following option is/are-

1. In a coordination entity, the central atom or ion is surrounded by a suitable number of neutral molecules or negative ions ( called ligands). 

2. Coordination number is also referred as ligancy.

3. Coordination polyhedrons is the spatial arrangement of the ligands that are directly attached to the central metal ion in the coordination sphere.

4. None of these.

Subtopic:  Introduction, Classification and Nomenclature |
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Optical isomerism is exhibited by among the following is/are:

1. [Cr(Ox)3]3+ 2. [PtCl2(en)2]2+
3. [Cr(NH3)2Cl2en]+ 4. All of the above
Subtopic:  Isomerism in Coordination Compounds |
 78%
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The incorrect statement(s) among the following options is/are:

1. Chlorophyll is a coordination compound of magnesium. 
2. Cis- Platin is a coordination compound of Platinum.
3. Gold is extracted by the addition of zinc metal. 
4. None of the above.

Subtopic:  Introduction, Classification and Nomenclature |
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The ligand(s)that show a chelating effect is/are:

1. Diethylenetriamine

2. Oxalato

3. Both 1 and 2

4. None of the above.

Subtopic:  Ligands |
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The correct splitting diagram of d orbitals in an octahedral crystal field is:

1. 2.
3. 4.  
None of these.
 

Subtopic:  VBT, CFT & their Limitations |
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The correct representation of potassium tetracyanidonickelate(II) is :

1. K3Ni(CN)4
2. KNi(CN)4
3. K2Ni(CN)4
4. K2Ni(CN)5

Subtopic:  Introduction, Classification and Nomenclature |
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The correct representation of pentaamminenitrito-O-cobalt(III) is :

1. Co(NH3)5(ONO)3+
2.  Co(NH3)5(ONO)2+
3. Co(NH3)5(ONO)2-
4.  Co(NH3)5(ONO)3-

Subtopic:  Introduction, Classification and Nomenclature |
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