$\mathrm{Out}<mspace\; width="1em"></mspace>\mathrm{of}<mspace\; width="1em"></mspace>{\mathrm{TiF}}_6^{2-},<mspace\; width="1em"></mspace>{\mathrm{CoF}}_6^{3-},<mspace\; width="1em"></mspace>{\mathrm{Cu}}_2{\mathrm{Cl}}_2<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NiCl}}_4^{2-}$ (At. no. Z of Ti = 22, CO = 27, Cu = 29, Ni = 28), the colourless species are

(a) ${\mathrm{TiF}}_6^{2-}<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{CoF}}_6^{3-}$

(b) ${\mathrm{Cu}}_2{\mathrm{Cl}}_2<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NiCl}}_4^{2-}$$$

(c) ${\mathrm{TiF}}_6^{2-}<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{Cu}}_2{\mathrm{Cl}}_2$

(d) ${\mathrm{CoF}}_6^{3-}<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NiCl}}_4^{2-}$

An example of a sigma bonded organometallic compound is

(a) ruthenocene                  (b) Grignard's reagent

(c) ferrocene                      (d) cobaltocene

The correct order of the stoichiometric of AgCl formed when AgNO₃ in excess is treated with the complexes CoCl₃.6NH₃, CoCl₃.5NH₃, and CoCl₃.4NH₃ respectively is:

1. 1 AgCl, 3 AgCl, 2 AgCl
2. 3 AgCl, 1 AgCl, 2 AgCl
3. 3 AgCl, 2 AgCl, 1 AgCl
4. 2 AgCl, 3AgCl,  1 AgCl

The hybridisation involved in complex [Ni(CN)₄]^2- is (Atomic number of Ni = 28)

(1) dsp²                               

(2) sp³

(3) d²sp²                             

(4) d²sp³

The complexes [CO(NH₃)₆][Cr(CN)₆] and [Cr(NH₃)₆][Co(CN)₆] are the examples of which type of isomerism?

(1) lonisation isomerism
(2) Coordination isomerism
(3) Geometrical isomerism
(4) Linkage isomerism

Aqueous solution of ${\mathrm{Ni}}^{2+}$ contains ${\left[\mathrm{Ni}({\mathrm{H}}_2\mathrm{O}{)}_6\right]}^{2+}$ and its magnetic moment is 2.83 BM. When ammonia is added in it, comment on the magnetic moment of solution :

(1) It will remain same

(2) It increases from 2.83 BM

(3)  It decreases from 2.83 BM

(4) It cannot be predicted theoretically

Which of the following is true about the complex $\left[{\mathrm{PtCl}}_2\right({\mathrm{H}}_2\mathrm{O}\left)\right({\mathrm{NH}}_3\left)\right]$ ?

(1) It exhibits geometrical isomerism

(2) It is paramagnetic complex

(3) It's geometry is tetrahedron 

(4) Platinum is ${\mathrm{sp}}^3$ hybridised 

Which of the following isomerism, exhibited by $\left[{\mathrm{CrCl}}_2\right(\mathrm{OH}{)}_2\left({\mathrm{NH}}_3{)}_2\right]$?

(1)Ionization     

(2) Geometrical

(3) Hydrate       

(4) Linkage

What is electronic arranegment of metal atom/ion in octahedral complex with ${\mathrm{d}}^4$ configuration , if ${∆}_0$< pairing energy ?

(a) ${\mathrm{t}}_{2\mathrm{g}}^4{\mathrm{e}}_{\mathrm{g}}^0$                       (b) ${\mathrm{e}}_{\mathrm{g}}^4<mspace\; width="1em"></mspace>{\mathrm{t}}_{2\mathrm{g}}^0$               (c) ${\mathrm{t}}_{2\mathrm{g}}^3{\mathrm{e}}_{\mathrm{g}}^1$           (d) ${\mathrm{e}}_{\mathrm{g}}^2{\mathrm{t}}_{2\mathrm{g}}^2$

Match List-I with List-II and select the correct answer using the codes given below :

                      List-I                                              List-II

(I) $[{\mathrm{FeF}}_6{]}^{3-}$                                                   (A) 1.73 BM

(II) $\left[\mathrm{Ti}\right({\mathrm{H}}_2\mathrm{O}{)}_6{]}^{3+}$                                             (B) 5.93 BM

(III) $\left[\mathrm{Cr}\right({\mathrm{NH}}_3{)}_6{]}^{3+}$                                            (C) 0.00 BM

(IV) $\left[\mathrm{Ni}\right({\mathrm{H}}_2\mathrm{O}{)}_6{]}^{2+}$                                             (D) 2.83 BM

(V)  $\left[\mathrm{Fe}\right(\mathrm{CN}{)}_6{]}^{4-}$                                               (E) 3.88 BM

          (I)    (II)   (III)   (IV)   (V)                       (I)    (II)   (III)   (IV)   (V) 

(a)      B      A       C       D      E                  (b)    B      A       E       D      C

(c)       B     C       D       E      A                 (d)     D     E       A       B       C