Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. The dose of nalorphene generally given is 1.5 mg.

Calculate the mass of 1.5 × 10−3m aqueous solution required for the above dose.
1. 13.22 g
2. 3.22 g
3. 11.22 g
4. 9.22 g

Subtopic:  Concentration Terms & Henry's Law |
 75%
Level 2: 60%+
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The amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution in methanol is:

1. 4.57 g 2. 3.57 g
3. 1.57 g 4. 12.57 g
Subtopic:  Concentration Terms & Henry's Law |
 81%
Level 1: 80%+
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The depression in the freezing point of water was observed for the same amount of acetic acid, trichloroacetic acid, and trifluoroacetic in the order of-

1. acetic acid < trichloroacetic acid < trifluoroacetic acid

2. acetic acid > trichloroacetic acid > trifluoroacetic acid

3.  acetic acid < trichloroacetic acid > trifluoroacetic acid

4. acetic acid > trichloroacetic acid < trifluoroacetic acid

 

Subtopic:  Depression of Freezing Point |
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The depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water will be:

 (Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1)

1. 0.32 K

2. 2.87 K

3. 0.65 K

4. 5.03 K

Subtopic:  Depression of Freezing Point |
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19.5 g of CH2FCOOH is dissolved in 500 g of water. The van’t Hoff factor and dissociation constant of fluoroacetic acid will be respectively: (Tf = 1.00 K )

1. 20.75 , 4.77 × 10–3 2. 1.075 ,  4.77 × 10–2
3. 2.073 , 3.07 × 10–4 4. 1.075 , 3.07 × 10–3
Subtopic:  Van’t Hoff Factor |
Level 3: 35%-60%
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100 g of liquid A (molar mass 140 g mol–1) was dissolved in 1000 g of liquid B (molar mass 180 g mol–1). The vapour pressure of pure liquid B was found to be 500 torrIf the total vapour pressure of the solution is 475 torr, the vapour pressure of pure liquid A will be:

1. 326 torr 2. 226 torr 
3. 360.7 torr 4. 280.7 torr
Subtopic:  Raoult's Law |
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Level 3: 35%-60%
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The major component of air is nitrogen with approximately 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K. if the Henry’s law constant for nitrogen at 298 K is 6.51 × 107 mm respectively, then the composition of nitrogen in air will be :

1. 12.4 × 10−5

2. 9.22 × 10−5

3. 3.54 × 10−5

4. 4.96 × 10−5

Subtopic:  Concentration Terms & Henry's Law |
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The amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27 °C is:

1. 1.02 g 2. 4.35 g
3. 2.87 g 4. 3.42 g
Subtopic:  Osmosis & Osmotic Pressure |
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If 22 g of benzene is dissolved in 122 g of CCl4, the mass percentage of CCl4 and benzene respectively are-

1. 15.28 %, 84.72% 

2. 84.72 %, 15.28 %

3. 8.72 %, 91.28%

4. 91.28 %, 8.72 %

Subtopic:  Concentration Terms & Henry's Law |
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The type of inter molecular interactions present in

(a) Methanol and Acetone (i) Van der Waal’s forces of attraction
(b) Acetonitrile and Acetone (ii) ion-dipole interaction
(iii) dipole-dipole interaction
 
(a) (b)
1. (iii) (ii)
2. (ii) (ii)
3. (iii) (iii)
4. (iii) (i)
Subtopic:  Azeotrope |
Level 3: 35%-60%
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