A compound A of formula C3H6Cl2 on reaction with alkali can give B of formula C3H6O or C of formula C3H4. B on oxidation gave a compound of the formula C3H7O2. C with dilute H2SO4 containing Hg2+ ion gave D of formula C3H6O, which with bromine and NaOH gave the sodium salt of C2H4O2. Then A is :
1. CH3CH2CHCl2
2. CH3CCl2CH3
3. CH2ClCH2CH2Cl
4. CH3CHClCH2Cl
Difficulty Level:
Identify the product (A) in following reaction series, (X)(Y)(Z)(A) :
1. CH3CHO
2. CH3CONH2
3. CH3COOH
4. CH3 - CH2-NHOH
Difficulty Level:
Vapour density of an organic compound is 23.0. It contains 52.17% of carbon and 13% of hydrogen. The compound gives iodoform test. The compound is:
1. ethanol
2. dimethyl ether
3. acetone
4. methanal
Difficulty Level:
Compound (A), C8H9Br , gives a white precipitate when warmed with alcholic AgNO3. Oxidation of (A) gives an acid (B), C8H6O4. (B) easily forms anhydride on heating. Identify the compound (A).
1.
2.
3.
4.
Difficulty Level:
Which of the following will give yellow precipitate with I2/NaOH?
1. CH3-CO-O-CO-CH3
4.Both (2) and (3)
Difficulty Level:
A nitrogeneous substance X is treated with red P/I2,AgNO2, HNO2 and the product so formed is further treated with NaOH solution, which produces blue colouration. X can be
1. CH3CH2NH2
2 CH3CH2NO2
3. CH3CH2ONO
4 (CH3)2CHNO2
Difficulty Level:
The compound which reacts fastest with Lucas reagent at room temperature is:
1. Butan-1-ol
2. Butan-2-ol
3. 2-methylpropan-1-ol
4. 2-methylpropan-2-ol
Difficulty Level:
Methanol and ethanol can be distinguished by the following:
1. By reaction with metallic sodium
2. By reaction with caustic soda
3. By heating with iodine and washing soda
4. By heating with zinc and inorganic mineral acid
Difficulty Level:
Identify (X) in the sequence :
(1) CH3-CH2-CH2OH
(2)
(3) CH3-O-CH2-CH3
(4) CH3-CH2-CHO
Difficulty Level:
In order to accomplish the following conversion, what reagent and conditions would be required?
1. Cold sodium hydroxide
2. Hot conc. sodium hydroxide
3. Potassium tertiary butoxide and heat
4. Hot water
Difficulty Level: