$\frac{{\mathrm{K}}_{\mathrm{p}}}{{\mathrm{K}}_{\mathrm{c}}}$ for the gaseous reaction:

$\mathrm{I}.<mspace\; width="1em"></mspace>2\mathrm{A}<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>3\mathrm{B}<mspace\; width="1em"></mspace>\rightleftharpoons 2\mathrm{C}$
$\mathrm{II}.<mspace\; width="1em"></mspace>2\mathrm{A}\rightleftharpoons 4\mathrm{B}$
$\mathrm{III}.<mspace\; width="1em"></mspace>\mathrm{A}+\mathrm{B}+2\mathrm{C}<mspace\; width="1em"></mspace>\rightleftharpoons 4\mathrm{D}$

Would be respectively:

1. (RT)^-3, (RT)², (RT)⁰ 

2. (RT)^-3, (RT)-², (RT)^-1 

3. (RT)^-3, (RT)², (RT) 

4. None of the above

N₂O₄ dissociates as ${\mathrm{N}}_2{\mathrm{O}}_4\left(\mathrm{g}\right)\rightleftharpoons 2{\mathrm{NO}}_2\left(\mathrm{g}\right)$ at 273 K and 2 atm pressure. The equilibrium mixture has a vapour density of 41. What will be the percentage degree of dissociation ?

1. 14.2%

2. 16.2%

3. 12.2%

4. 87.8%

Inert gas is added to the equilibrium ${\mathrm{PCl}}_5(\mathrm{g})\hspace{0.17em}\rightleftharpoons \hspace{0.17em}{\mathrm{PCl}}_3(\mathrm{g})$ $+$ ${\mathrm{Cl}}_2\left(\mathrm{g}\right)$ at constant pressure. The degree of dissociation will :

1. Remain unchanged

2. Decrease

3. Increase

4. Decrease or increase but cannot be predicted with certainty

Dissociation of phosphorus pentachloride is favoured by:

1. High temperature and high pressure

2. High temperature and low pressure

3. Low temperature and low pressure

4. Low temperature and high pressure

1. I, and II

2. II, and III

3. I, and III

4. I,II ,and III

The stability product constant K_sp of Mg(OH)₂ is 9.0 X 10^-12. If a solution is 0.010 M with respect to Mg²⁺ ion, what is the maximum hydroxide ion concentration which could be present without causing the precipitation of Mg(OH)₂ ?

1. 1.5 X 10^-7 M

2. 3.0 X 10^-7 M

3. 1.5 X 10^-5 M

4. 3.0 X 10^-5 M

The amount of CaC₂O₄ (molecular weight =128) will dissolve in distilled water to make 1 liter of a saturated solution is: 

[K_sp (CaC₂O₄) = 2.5 x 10^-9 ]

1. 0.0064 g             
2. 0.1280 g
3. 0.0128 g           
4. 1.2800 g

What substance could be added to one liter of water to serve as a buffer?

1. One mole of \(CH_ 3 COO H\) and 0.5 moles of \(NaOH\)

2. One mole of \(NH_4Cl\) and one mole of \(HCl\)

3. One mole of \(NH_4OH\) and one mole of \(NaOH\)

4. One mole of \(CH_ 3 COO H\) and one mole of \(HCl\)

Acoording to Bronsted-Lowry concept, the correct order of relative strength of bases follows the order

1. CH₃COO^- > Cl^- > OH^-

2. CH₃COO^- > OH^- > Cl^-

3. OH^- > CH₃COO^- > Cl^-

4. OH^- > Cl^-> CH₃COO^-

pOH of H₂O is 7.0 at 298K. If water is heated at 350K, which of the following statement should be true ?

(1) pOH will decrease

(2) pOH will increase

(3) pOH will remain 7.0

(4) Concentration of H⁺ ions will increase but that of OH^- will decrease.