The reaction of propanamide with ethanolic sodium hydroxide and bromine will give:

1. Ethylamine 2. Methylamine
3. Propylamine 4. Aniline

Subtopic:  Amines - Preparation & Properties |
 74%
Level 2: 60%+
NEET - 2020
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A compound "A", when reacted with PCl5 and then with ammonia, gives "B". "B" on treatment with bromine and caustic potash produces "C". "C" on treatment with NaNO2 and HCl at C and then boiling produces ortho-cresol. Compound "A" is:

1. o-Toluic acid

2. o-Chlorotoluene

3. o-Bromotoluene

4. m-Toluic acid

Subtopic:  Amines - Preparation & Properties |
 73%
Level 2: 60%+
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An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol, and N2 gas was evolved. (A) on warming with CHCl3 and caustic potash gave (C) which on reduction gave isopropylmethylamine. The structure of (A) is:

1. 2.
3. 4.
Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 64%
Level 2: 60%+
AIPMT - 2012
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Which of the following compounds is most basic?

1. 2.
3. 4.
Subtopic:  Amines - Preparation & Properties |
 77%
Level 2: 60%+
AIPMT - 2011
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D is N-methyl aniline in the given below sequence of reaction:
\(\text A\xrightarrow{\bf\text{ reduction }}\text B\xrightarrow{\bf\text {CHCl}_3\text{/KOH}}\text C\xrightarrow{\bf\text{ reduction }}\text D\)

Structure of A can be:

1.   2.
3.  
\(\mathrm{CH_3NH_2 }\)
4.
Subtopic:  Amines - Preparation & Properties |
 70%
Level 2: 60%+
AIPMT - 2000
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The products formed when Aniline reacts with Br2 water, and NaNO2/HCl will be, respectively:

1. p-Bromoaniline; p-Chloroaniline
2. 2,4,6-Tribromoaniline; p-Chloroaniline
3. 2,4,6-Tribromoaniline; Benzenediazoniumchloride
4. p-Bromoaniline; Benzenediazoniumchloride
Subtopic:  Amines - Preparation & Properties |
 86%
Level 1: 80%+
AIPMT - 1998
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Aniline when diazotized in cold and then treated with dimethyl aniline gives a coloured product. Its structure would be:

1.
2.
3.
4.
Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 79%
Level 2: 60%+
AIPMT - 2004
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Which chemical reaction leads to the formation of isocyanide?

1. Reimer Tiemann reaction.
2. Carbylamine reaction.
3. Hoffmann bromamide reaction.
4. None of the above.

Subtopic:  Amines - Preparation & Properties |
 90%
Level 1: 80%+
AIPMT - 1999
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The final product C, obtained in this reaction, would be:

1. 2.
3. 4.
Subtopic:  Amines - Preparation & Properties |
 75%
Level 2: 60%+
AIPMT - 2003
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An aromatic compound ‘A’ on treatment with ammonia and heating forms compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of molecular formula C6H7N. The Substrate 'A' is:

1. Aniline

2. Benzoic acid 

3. Benzamide

4. Benzamine

Subtopic:  Mechanism |
 70%
Level 2: 60%+
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