D is N-methyl aniline in the given below sequence of reaction:
\(\text A\xrightarrow{\bf\text{ reduction }}\text B\xrightarrow{\bf\text {CHCl}_3\text{/KOH}}\text C\xrightarrow{\bf\text{ reduction }}\text D\)

Structure of A can be:

1.   2.
3.  
\(\mathrm{CH_3NH_2 }\)
4.

Subtopic:  Amines - Preparation & Properties |
 70%
Level 2: 60%+
AIPMT - 2000
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The products formed when Aniline reacts with Br2 water, and NaNO2/HCl will be, respectively:

1. p-Bromoaniline; p-Chloroaniline
2. 2,4,6-Tribromoaniline; p-Chloroaniline
3. 2,4,6-Tribromoaniline; Benzenediazoniumchloride
4. p-Bromoaniline; Benzenediazoniumchloride
Subtopic:  Amines - Preparation & Properties |
 86%
Level 1: 80%+
AIPMT - 1998
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Aniline when diazotized in cold and then treated with dimethyl aniline gives a coloured product. Its structure would be:

1.
2.
3.
4.
Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 79%
Level 2: 60%+
AIPMT - 2004
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Which chemical reaction leads to the formation of isocyanide?

1. Reimer Tiemann reaction.
2. Carbylamine reaction.
3. Hoffmann bromamide reaction.
4. None of the above.

Subtopic:  Amines - Preparation & Properties |
 90%
Level 1: 80%+
AIPMT - 1999
Hints

The final product C, obtained in this reaction, would be:

1. 2.
3. 4.
Subtopic:  Amines - Preparation & Properties |
 75%
Level 2: 60%+
AIPMT - 2003
Hints

A method for the identification of primary, secondary and tertiary amines is:

1. Azo-dye test

2. Carbylamine test

3. Hinsberg’s test

4. None of these

Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 82%
Level 1: 80%+
Hints

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Aromatic primary amines cannot be prepared by Gabriel phthalimide synthesis because :

1. Alkyl halides do not undergo electrophilic substitution with the anion formed by the phthalimide
2. Alkyl halides do not undergo nucleophilic substitution with the anion formed by the phthalimide
3. Aryl halides do not undergo nucleophilic substitution with the anion formed by the phthalimide
4. Aryl halides do not undergo electrophilic substitution with the anion formed by the phthalimide

Subtopic:  Amines - Preparation & Properties |
 73%
Level 2: 60%+
Hints

C6H5N2Cl+H3PO2+H2O:

The product from the above reaction would be -

1.C6H5NC

2.C6H6CH3

3.C6H5CN

4.C6H6

 

Subtopic:  Amines - Preparation & Properties |
 84%
Level 1: 80%+
Hints

The primary amine is -

1. (CH3)2CHNH2

2. CH3(CH2)2NH-CH3

3. CH3(CH2)2N(CH3)2

4. None of the above

Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 90%
Level 1: 80%+
Hints

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Which of the following is a secondary amine is -

1.CH3(CH2)2NH2
2.(CH3CH2)2NCH3
3.C6H5NHCH3
4.(CH3)3NH2

Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 87%
Level 1: 80%+
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