What is the rate equation for reaction 2A+ B C if the order of the reaction is zero ?

1. k [A]0 [B]0

2. k [A]1[B]0

3. k [A]1[B]1

4. None of these

Subtopic:  Order, Molecularity and Mechanism |
 89%
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For a certain reaction large fraction of molecules have energy more than the threshold energy, yet why the rate of reaction is very slow.It is due to improper: 

1. Orientation of colliding molecules.

2. Energy of colliding molecules.

3. Volume of colliding molecules.

4. Entropy of colliding molecules.

Subtopic:  Arrhenius Equation |
 86%
From NCERT
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For a general reaction A  B, the plot of the concentration of A vs. time is given in the figure.
 

The slope of the curve will be:

1. -k 2. -k/2
3. -k2 4. -k/3
Subtopic:  Definition, Rate Constant, Rate Law |
 89%
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The conversion of molecules X to Y follows second order kinetics. If concentration of X is increased to three times how will it affect the rate of formation of Y?

1. 6 times

2. 9 times

3. 12 times

4. 3 times

 

Subtopic:  Definition, Rate Constant, Rate Law |
 84%
From NCERT
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The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. The activation energy of the chemical reaction is ?

1. 55.6 Jmol-1

2. 45.6 kJmol-1

3. 52.9 kJmol-1

4. 45.7 Jmol-1

Subtopic:  Arrhenius Equation |
 65%
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The activation energy for the reaction 2HI(g) → H2(g)+ I2(g) is 209.5 kJ mol−1 at 581K. What is the fraction of molecules of reactants having energy equal to or greater than activation energy?

1. 2.31 × 10-16
2. 3.52 × 10-18
3. 1.47 × 10-19
4. 2.13 × 10-20

Subtopic:  Arrhenius Equation |
 51%
From NCERT
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The rate constant for a first order reaction is 60 s–1. How much time will it take to reduce the initial concentration of the reactant to its 1/16th value?

1. 2.3 × 10-2 s
2. 4.6 × 10-2 s
3. 3.1 × 10-3 s
4. 1.4 × 10-2 s

Subtopic:  First Order Reaction Kinetics |
 77%
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A first-order reaction takes 40 min for 30 % decomposition. The half life of the reaction will be: 

1. 88.8 min 2. 94.3 min
3. 67.2 min 4. 77.7 min

Subtopic:  First Order Reaction Kinetics |
 61%
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The rate constant for the decomposition of hydrocarbons is 2.418 × 10–5 s–1 at 546 K. If the energy of activation is 179.9 kJ/mol, the value of the pre-exponential factor will be:

1. 4.0 × 1012 s-1
2. 7.8 × 10-13 s-1
3. 3.8 × 10-12 s-1
4. 4.7 × 1012 s-1

Subtopic:  Arrhenius Equation |
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For a reaction A  Product, with k = 2.0 × 10–2 s–1, if the initial concentration of A is 1.0 mol L-1, the concentration of A after 100 seconds would be :

1. 0.23 mol L-1 2. 0.18 mol L-1
3. 0.11 mol L-1 4. 0.13 mol L-1
Subtopic:  First Order Reaction Kinetics |
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