Thefolowingmechanismhasbeen
proposedfortheexothermiccatalyzed
complexreaction
A+BslowfastIABk1AB+Ik2P+A
Ifk1ismuchsmallerthank2,themost
suitablequalitativeplotofpotential
energyP.E.versus
reactionco-ordinateR.C.for
theabovereaction

1.                    

2.  

3.                   

4. 

Subtopic:  Arrhenius Equation |
 53%
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The plot of log k vs 1T helps to calculate : 

1. Energy of activation.
2. Rate constant of reaction.
3. Order of the reaction.
4. Energy of activation as well as the frequency factor.

Subtopic:  Arrhenius Equation |
 63%
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The effect of a catalyst in a chemical reaction is
to change the
1. Acivation energy
2. Equilibrium concentration
3. Heat of reaction
4. Final products

Subtopic:  Arrhenius Equation |
 97%
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ForreactionAB,therateconstantk1=A1e-Ea1/RTandforthereactionXy,therateconstantk2=A2e-Ea2/RT.IfA1=108A2=1010andEa1=600cal/mol,Ea2=1800cal/mol,thenthetemperatureatwhichk1=k2isgiven:R=2cal/K-mol

1.  1600K

2.  1200x4.606K

3.  12004.606K

4.  6004.606K

Subtopic:  Arrhenius Equation |
 57%
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A hydrogenation reaction is carried out at 500 K. If the same reaction is carried out in presence of a catalyst at the same rate with same frequency factor, the temperature required is 400 K the activation energy of the reaction, if the catalyst lowers the activation energy barrier by 16 kJ/mol is: 

1.  100 kJ/mol

2.  80 kJ/mol

3.  60 kJ/mol

4.  None of th above

Subtopic:  Arrhenius Equation |
 70%
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AgaseouscompoundAreactsbythree
independentfirst-orderprocesses
(asshowninthefigure)withrate
constant
2x10-3
3x10-3
and
1.93x10-3sec-I
forproducts
B,C,andDrespectively.Ifinitiallypure
Awastakeninaclosedcontainerwith
P=8atm,thenthepartialpressure
ofB(inatm)after100secfromthe
startofexperiment.

       

1.  0.288

2.  0.577

3.  1.154

4.  None of these

 

Subtopic:  First Order Reaction Kinetics |
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The gaseous decomposition reaction, A(g) 2B(g) + C(g) is observed to first order over the excess of liquid water at 25°C It is found that after 10 minutes the total pressure of the system is 188 torr and after a very long time, it is 388 torr. The rate constant of the reaction inhr-1 is :
[Given : vapour pressure of H2O at 25° is 28 torr (In 2 = 0.7, In 3 = 1.1, In 10 = 2.3)]

1.  0.02

2.  1.2

3.  0.2

4.  None of these

Subtopic:  First Order Reaction Kinetics |
 58%
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ThereactionAg+2BgCgis
anelementaryreaction.Inanexperiment
involvingthisreaction,theinitialpartial
pressuresofAandBarePA=0.40atm
andPB=1.0atmrespectively.
WhenPC=0.3atm,therateofthereaction
relativetotheinitialrateis:

1.  112

2.  150

3.  125

4.  Noneofthese

Subtopic:  Order, Molecularity and Mechanism |
 58%
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Theforwardrateconstantfortheelementary
reversiblegaseousreaction
C2H62CH3is1.57x10-3s-1at100K
Whatistherateconstantforthebackwardreaction
atthistemperatureif10-4molesofCH3and10
molesofC2H6arepresentina10litervesselat
equilibrium.

1.  1.57x109Lmol-1s-1 

2.  1.57x1010Lmol-1s-1

3.  1.57x1011Lmol-1s-1

4.  1.57x107Lmol-1s-1

Subtopic:  Order, Molecularity and Mechanism |
 60%
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For the reaction, \(\mathrm{N}_2+3 \mathrm{H}_2 \rightarrow 2 \mathrm{NH}_3,\) if, \(\dfrac{d[NH_{3}]}{dt} \ = \ 2\times 10^{-4} \ mol \ L^{-1} \ s^{-1}\), the value of  \(\dfrac{-d[H_{2}]}{dt}\) would be:
1. \(3 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
2. \(4 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
3. \(6 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
4. \(1 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 85%
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AIPMT - 2009
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