The vapour density of undecomposed N2O4 is 46. When heated, vapour density decreases to 24.5 due to its dissociation to NO2. The percent dissociation of N2O4 at the final temperature is:
1. 87
2. 60
3. 40
4. 70
Which solution will have the highest boiling point ?
1. 1 (M) C6H12O6 solution
2. 1 (M) NaCl solution
3. 1 (M) BaCl2 solution
4. 1 (M) CO(NH2)2 solution
20g of naphthoic acid (C11H8O2) dissolved in 50g of benzene (Kf=1.72 K Kg mol-1) shows a depression in freezing point of 2K. The Vant Hoff factor is?
1. 0.5
2. 0.1
3. 2
4. 3
When 0.1 m CH3COOH is present in a solvent it shows elevation in boiling point of 0.75. Acid dissociation constant will be -(Kb=5 K Kg mol-1) (1M =1m)
(1) 5 X 10-2
(2) 5 X 10-3
(3) 10-2
(4) 10-3
A solute x when dissolved in solvent associates to form a pentamer. The value of van't hoff factor (i) for the solute will be:-
1. 0.5
2. 5
3. 0.2
4. 0.1
The van't Hoff factor of a 0.005 M aqueous solution of KCl is 1.95. The degree of ionisation of KCl is-
1. 0.95
2. 0.97
3. 0.94
4. 0.96
K4[Fe(CN)6] is 60% ionised. Then the value of Van't Hoff factor is
1. 1.6
2. 2.4
3. 3
4. 3.4
The van't Hoff factor [i] for a dilute aqueous solution of the strong electrolyte barium hydroxide is?
(1) 0
(2) 1
(3) 2
(4) 3
Which one of the following elctrolytes has the same value of van't Hoff's factor(i) as
that of Al2(SO4)3 (if all are 100% ionised)?
1. K2SO4
2. K3[Fe(CN)6]
3. Al(NO3)3
4. K4[Fe(CN)6]
The van't Hoff factor, i for a compound which undergoes dissociation in one solvent and
association in other solvent is respectively.
1. less than one and less than one
2. greater than one and less than one
3. greater than one and greater than one
4. less than one and greater than one