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What is the correct electronic configuration of the central atom in \(K_{4}FeCN_{6}\) based on crystal field theory:

1. \(e^{4}   t_{2 g}^{    2}\) 2. \(t_{2 g}^{    4}   e_{g}^{2}\)
3. \(t_{2 g}^{    6}   e_{g}^{0}\) 4. \(e^{3}   t_{2 g}^{  3}\)

Subtopic:  VBT, CFT & their Limitations |
 81%
Level 1: 80%+
NEET - 2019
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The  complex ion that does not expected to absorb visible light is:

1. [Ni(CN)4]2-

2. [Cr(NH3)6]3+

3. [Fe(H2O)6]2+

4. [Ni(H2O)6]2+

Subtopic:  Organometallic Complexes & their Uses |
 77%
Level 2: 60%+
AIPMT - 2010
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An anticancer agent among the following is:

1. \(\text { mer} - \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}\right] \) 2. \(\text { cis -} \left[\mathrm{PtCl}_2\left(\mathrm{NH}_3\right)_2\right] \)
3. \(\text {cis -} \mathrm{K}_2\left[\mathrm{Pt} \mathrm{Cl}_2 \mathrm{Br}_2\right] \) 4. \(\mathrm{NH}_2 \mathrm{CoCl}_4\)
Subtopic:  Isomerism in Coordination Compounds |
 91%
Level 1: 80%+
AIPMT - 2014
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An ion that has magnetic moment 2.83 BM is:
(Atomic Number: Ti=22, Cr=24, Mn=25, Ni=28)

1. Ti3+

2. Ni2+

3. Cr3+

4. Mn2+

Subtopic:  VBT, CFT & their Limitations |
 90%
Level 1: 80%+
AIPMT - 2014
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Cobalt(III) chloride forms several octahedral complexes with ammonia.
A compound among the following that does not give a test for chloride ions with silver nitrate at 25 °C is:

1. CoCl3. 3NH3 2. CoCl3. 4NH3
3. CoCl3. 5NH3 4. CoCl3. 6NH3
Subtopic:  Introduction, Classification and Nomenclature |
 81%
Level 1: 80%+
NEET - 2015
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An ion, among the following, that has a magnetic moment of 2.84 BM is:
(At. no. Ni = 28, Ti = 22, Cr = 24, Co = 27)

1. Ni2+
2. Ti3+
3. Cr2+
4. Co2+

Subtopic:  VBT, CFT & their Limitations |
 81%
Level 1: 80%+
NEET - 2015
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The IUPAC name of complex ion, [Fe(CN)6]3- is:

1. Hexacyanoiron(III) ion

2. Hexacyanitoferrate(III) ion

3. Tricynoferrate(III) ion

4. Hexacyanidoferrate(III) ion

Subtopic:  Introduction, Classification and Nomenclature |
 78%
Level 2: 60%+
NEET - 2015
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The hybridization involved in the complex NiCN42-is:
(Atomic number of Ni=28)

1. dsp2 2. sp3
3. d2sp2 4. d2sp3

Subtopic:  VBT, CFT & their Limitations |
 83%
Level 1: 80%+
NEET - 2015
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The low spin complex among the following is:

1. \(\mathrm{Fe}(\mathrm{CN})_6^{3-} \) 2. \(\mathrm{Co}\left(\mathrm{NO}_2\right)_6^{3-} \)
3. \(\mathrm{Mn}(\mathrm{CN})_6^{3-} \) 4. All of these
Subtopic:  VBT, CFT & their Limitations |
 83%
Level 1: 80%+
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Iron carbonyl, FeCO5, is classified as:

1. Tetranuclear 2. Mononuclear
3. Trinuclear 4. Dinuclear
Subtopic:  Organometallic Complexes & their Uses |
 79%
Level 2: 60%+
NEET - 2018
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