1. | Internal energy | 2. | Enthalpy |
3. | Activation energy | 4. | Entropy |
A reaction having equal energies of activation for forward and reverse reaction has:
1. ΔG = 0
2. ΔH = 0
3. ΔH = ΔG = ΔS = 0
4. ΔS = 0
In a reaction, A + B → Product, the rate is doubled when the concentration of B is doubled, and the rate increases by a factor of 8, when the concentrations of both the reactants (A and B) are doubled. The rate law for the reaction can be written as:
1. Rate = k[A][B]2
2. Rate = k[A]2[B]2
3. Rate = k[A][B]
4. Rate = k[A]2[B]
In a zero-order reaction for every 10 °C rise of temperature, the rate is doubled.
If the temperature is increased from 10 °C to 100 °C, the rate of the reaction will become:
1. 256 times
2. 512 times
3. 64 times
4. 128 times
Which of the following statements about the order of reaction is incorrect?
1. | Order is not influenced by the stoichiometric coefficient of the reactants. |
2. | Order of reaction is the sum of power to the concentration terms of reactants to express the rate of reaction. |
3. | The order of reaction is always a whole number. |
4. | Order can be determined by experiments only. |
During the kinetic study of the reaction, 2A + B\( \rightarrow\)C + D, following results were obtained:
Run | [A)/ mol L-1 | [B)/ mol L-1 | Initial rate of formation of D/mol L-1 |
I | 0.1 | 0.1 | \(6.0 \times 10^{- 3}\) |
II | 0.3 | 0.2 | \(7.2 \times 10^{- 2}\) |
III | 0.3 | 0.4 | \(2.88 \times \left(10\right)^{- 1}\) |
IV | 0.4 | 0.1 | \(2.40 \times \left(10\right)^{- 2}\) |
Based on the above data which one of the following is correct?
1. rate= k[A]2[B]
2. rate= k[A][B]
3. rate= k[A]2[B]2
4. rate= k[A][B]2
The half-life period of a first-order reaction is 1386 s. The specific rate constant of the reaction is:
1.
2.
3.
4.
In the reaction,
3Br2(l)+3H2O(l)
The rate of appearance of bromine (Br2) is related to the rate of disappearance of bromide ions:
1.
2.
3.
4.
The reaction of hydrogen and iodine monochloride is given as:
H2(g) + 2ICl(g) → 2HCl(g) + I2(g)
This reaction is of first order with respect to H2(g) and ICl(g), for which of the following proposed mechanisms:
Mechanism A:
H2(g) + 2ICl(g) → 2HCl(g) + I2(g)
Mechanism B:
H2(g) + ICl(g) →HCl(g) + HI(g); slow
HI(g) + ICl(g) →HCl(g) + I2(g); fast
1. B Only
2. A and B both
3. Neither A nor B
4. A only