When the initial concentration of the reactant is doubled, the half-life period of a zero-order reaction:

1. is halved 2. is doubled
3. is tripled 4. remains unchanged

Subtopic:  Order, Molecularity and Mechanism |
 78%
Level 2: 60%+
NEET - 2018
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Which quantity is altered when a catalyst is introduced during a chemical reaction?
1. Internal energy 2. Enthalpy
3. Activation energy 4. Entropy
Subtopic:  Definition, Rate Constant, Rate Law |
 93%
Level 1: 80%+
NEET - 2016
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A reaction having equal energies of activation for forward and reverse reaction has:

1. ΔG = 0

2. ΔH = 0

3. ΔH = ΔG = ΔS = 0

4. ΔS = 0

Subtopic:  Arrhenius Equation |
 73%
Level 2: 60%+
AIPMT - 2013
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In a reaction, A + B → Product, the rate is doubled when the concentration of B is doubled, and the rate increases by a factor of 8, when the concentrations of both the reactants (A and B) are doubled. The rate law for the reaction can be written as:

1. Rate = k[A][B]2

2. Rate = k[A]2[B]2

3. Rate = k[A][B]

4. Rate = k[A]2[B]

Subtopic:  Definition, Rate Constant, Rate Law |
 78%
Level 2: 60%+
AIPMT - 2012
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In a zero-order reaction for every 10 °C rise of temperature, the rate is doubled.
If the temperature is increased from 10 °C to 100 °C, the rate of the reaction will become:

1. 256 times

2. 512 times

3. 64 times

4. 128 times

Subtopic:  First Order Reaction Kinetics |
 86%
Level 1: 80%+
AIPMT - 2012
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Which of the following statements about the order of reaction is incorrect?

1. Order is not influenced by the stoichiometric coefficient of the reactants.
2. Order of reaction is the sum of power to the concentration terms of reactants to express the rate of reaction.
3. The order of reaction is always a whole number.
4. Order can be determined by experiments only.
Subtopic:  Definition, Rate Constant, Rate Law |
 80%
Level 1: 80%+
AIPMT - 2011
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During the kinetic study of the reaction, 2A + B\( \rightarrow\)C + D, following results were obtained:

Run [A)/ mol L-1 [B)/ mol L-1 Initial rate of
formation of D/mol L-1
I 0.1 0.1 \(6.0 \times 10^{- 3}\)
II 0.3 0.2 \(7.2 \times 10^{- 2}\)
III 0.3 0.4 \(2.88 \times \left(10\right)^{- 1}\)
IV 0.4 0.1 \(2.40 \times \left(10\right)^{- 2}\)


Based on the above data which one of the following is correct?

1. rate= k[A]2[B]

2. rate= k[A][B]

3. rate= k[A]2[B]2

4. rate= k[A][B]2

Subtopic:  Definition, Rate Constant, Rate Law |
 78%
Level 2: 60%+
AIPMT - 2010
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The half-life period of a first-order reaction is 1386 s. The specific rate constant of the reaction is:

1. 5.0×10-3s-1

2. 0.5×10-2s-1

3. 0.5×10-3s-1

4. 5.0×10-2s-1

Subtopic:  Definition, Rate Constant, Rate Law |
 85%
Level 1: 80%+
AIPMT - 2009
Hints

For the reaction, \(\mathrm{N}_2+3 \mathrm{H}_2 \rightarrow 2 \mathrm{NH}_3,\) if, \(\dfrac{d[NH_{3}]}{dt} \ = \ 2\times 10^{-4} \ mol \ L^{-1} \ s^{-1}\), the value of  \(\dfrac{-d[H_{2}]}{dt}\) would be:
1. \(3 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
2. \(4 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
3. \(6 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
4. \(1 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 86%
Level 1: 80%+
AIPMT - 2009
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In the reaction, 
BrO3-(aq)+5Br-(aq)+6H+ 3Br2(l)+3H2O(l) 
The rate of appearance of bromine (Br2) is related to the rate of disappearance of bromide ions:

1. d[Br2]dt=-35d[Br-]dt

2. d[Br2]dt=-53d[Br]dt

3. d[Br2]dt=53d[Br-]dt

4. d[Br2]dt=35d[Br-]dt

Subtopic:  Definition, Rate Constant, Rate Law |
 86%
Level 1: 80%+
AIPMT - 2009
Hints