The false statement regarding hydrides from the 15th group is:
| 1. | NH3 > PH3 > AsH3 > SbH3 > BiH3 | Thermal stability |
| 2. | N-H > P-H > As-H > Sb-H > Bi-H | E-H bond dissociation enthalpy |
| 3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 | Reducing character |
| 4. | NH3 > PH3 > AsH3 > SbH3 > BiH3 | Basicity |
Which of the following statements is false?
| 1. | H3PO2, H3PO3 and H3PO4 all are tribasic and reducing in nature. |
| 2. | Amongst anions \(NO_{3}^{-}\), \(SO_{3}^{2-}\), \(CO_{3}^{2-}\), and \(BO_{3}^{3-}\), only \(SO_{3}^{2-}\) have pπ-dπ bonding . |
| 3. | Amongst anions \(SO_{3}^{2-}\), \(SO_{4}^{2-}\), \(S_{2}O_{4}^{2-}\) and \(HSO_{4}^{-}\), \(SO_{3}^{2-}\) is basic and reducing in nature. |
| 4. | Number of lone pair(s) of electrons on Xe atoms in XeF2, XeF4 and XeF6 are 3, 2 and 1 respectively._ |
The species among the following that does not exist is-
1.
2.
3.
4.
Which of the following reactions does not exhibit the oxidising behaviour of H2SO4?
1. Cu + 2H2SO4 → CuSO4 + SO2 + 2H2O
2. 3S + 2H2SO4 → 3SO2 + 2H2O
3. C + 2H2SO4 → CO2 + 2SO2 + 2H2O
4. CaF2 + H2SO4 → CaSO4 + 2HF
Match the compounds given in Column-I with the shape given in Column-II and mark the correct option.
| Column-I | Column-II | ||
| A. | XeF6 | 1. | Distorted octahedral |
| B. | XeO3 | 2. | Square planar |
| C. | XeOF4 | 3. | Pyramidal |
| D. | XeF4 | 4. | Square pyramidal |
| 1. | A-1, B-2, C-4, D-3 | 2. | A-4, B-3, C-1, D-2 |
| 3. | A-4, B-1, C-2, D-3 | 4. | A-1, B-3, C-4, D-2 |
The strong reducing behaviour of H3PO2 is due to:
1. Presence of one -OH group and two P-H bonds.
2. High electron gain enthalpy of phosphorus.
3. High oxidation state of phosphorus.
4. Presence of two -OH groups and one P-H bond.
The basic structural unit of silicates is:
1. (SiO4)4–
2. (SiO3)2–
3. (SiO4)2–
4. (SiO)
False statement regarding PCl5 is:
| 1. | PCl5 molecule is non-reactive. |
| 2. | Three equatorial P-Cl bonds make an angle of 120° with each other. |
| 3. | Two axial P-Cl bonds make an angle of 180° with each other. |
| 4. | Axial P-Cl bonds are longer than equatorial P-Cl bonds. |
The correct structure of tribromo octoxide is:
| 1. | |
| 2. | |
| 3. | |
| 4. |