| 1. | Weak acid and it's salt with a strong base. |
| 2. | Equal volumes of equimolar solutions of weak acid and weak base. |
| 3. | Strong acid and its salt with a strong base. |
| 4. | Strong acid and its salt with a weak base. (The pKa of acid = pKb of the base) |
| 1. | \(1 \times 10^{-4}\) |
| 2. | \(1 \times 10^{-6} \) |
| 3. | \(1 \times 10^{-5} \) |
| 4. | \(1 \times 10^{-3} \) |
| 1. | where the forward and reverse reactions have stopped. |
| 2. | whose rate law is of zero order. |
| 3. | where individual molecules are still reacting, but there is no net change in the system. |
| 4. | in which all components are in the same phase. |
| 1. | –13.73 cal | 2. | 1372.60 cal |
| 3. | –137.26 cal | 4. | –1381.80 cal |