| 1. | The \(\pi^*\) antibonding molecular orbital has a node between the nuclei. |
| 2. | In the formation of a bonding molecular orbital, the two electron waves of the bonding atoms reinforce each other. |
| 3. | Molecular orbitals obtained from \(2P_x\) and \(2P_y\) orbitals are symmetrical around the bond axis. |
| 4. | A \(\pi-\)bonding molecular orbital has larger electron density above and below the internuclear axis. |
| 1. | 0 |
| 2. | +1 |
| 3. | -1 |
| 4. | 0 in some resonance structures, –1 in other resonance structures |
| 1. | One | 2. | Three |
| 3. | Two | 4. | Four |
| a. | |
b. | ![]() |
| c. | ![]() |
d. | ![]() |
| 1. | LP-LP > BP-BP > LP-BP |
| 2. | LP-BP > BP-BP > LP-LP |
| 3. | LP-LP > LP-BP > BP-BP |
| 4. | BP-BP > LP-BP > LP-LP |
| List-I (Molecules) |
List-II (Shape) |
||
| (a) | NH3 | (i) | Square pyramidal |
| (b) | ClF3 | (ii) | Trigonal bipyramidal |
| (c) | PCl5 | (iii) | Trigonal pyramidal |
| (d) | BrF5 | (iv) | T-shape |
| (a) | (b) | (c) | (d) | |
| 1. | (ii) | (iii) | (iv) | (i) |
| 2. | (iii) | (iv) | (ii) | (i) |
| 3. | (iv) | (iii) | (i) | (ii) |
| 4. | (iii) | (iv) | (i) | (ii) |
| 1. | \(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_3<\mathrm{NH}_4^{+}<\mathrm{CO}_2 \) |
| 2. | \(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+}<\mathrm{NH}_3<\mathrm{CO}_2 \) |
| 3. | \(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+}=\mathrm{NH}_3<\mathrm{CO}_2 \) |
| 4. | \(\mathrm{CO}_2<\mathrm{NH}_3<\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+} \) |
| 1. | A and C only | 2. | C and B only |
| 3. | A, B, and C | 4. | None of these |