| 1. | 7.00 | 2. | 7.87 |
| 3. | 5.13 | 4. | 6.13 |
| 1. | 4 : 5 | 2. | 10 : 1 |
| 3. | 5 : 4 | 4. | 1 : 10 |
| 1. | Weak acid and it's salt with a strong base. |
| 2. | Equal volumes of equimolar solutions of weak acid and weak base. |
| 3. | Strong acid and its salt with a strong base. |
| 4. | Strong acid and its salt with a weak base. (The pKa of acid = pKb of the base) |
| 1. | \(1 \times 10^{-4}\) |
| 2. | \(1 \times 10^{-6} \) |
| 3. | \(1 \times 10^{-5} \) |
| 4. | \(1 \times 10^{-3} \) |
| 1. | Keq = \(\dfrac{[Cu(NH_3)_4^{2+}][OH^-]}{[NH_3]}\) |
| 2. | Keq = \(\dfrac{[Cu(NH_3)_4^{2+}][2~OH^-]}{[4~NH_3]}\) |
| 3. | Keq = \(\dfrac{[Cu(NH_3)_4^{2+}][OH^-]^2}{[NH_3]^4}\) |
| 4. | Keq = \(\dfrac{[Cu(NH_3)_4^{2+}][2~OH^-]^2}{[4~NH_3]^4}\) |
Consider the following statements:
| I. | Ionic product of water KW cannot change with temperature. |
| II. | The value of the equilibrium constant is independent of the initial concentration of the reactant and products. |
| III. | The equilibrium constant for an exothermic reaction decreases as the temperature increases. |
Which of the above statements is true?
1. I and II only
2. I and III only
3. II and III only
4. I, II, and III
| Assertion (A): | \(Ni(s)+4CO(g)\rightleftharpoons Ni(CO)_4(g)\\ \text{For the above reaction,}\\ K_C=\frac{[Ni(CO)_4]}{[CO]^4}\) |
| Reason (R): | For heterogeneous equilibrium, the concentrations of pure solids or liquids are not considered in the expression of the equilibrium constant. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |