For N2 + 3H2 2NH3, one mole of N2 and three moles of H2 are at pressure of 4 atm. Equilibrium pressure is found to be 3 atm. Hence, Kp is

1.    1/(0.5)x(0.15)3               2. 1/(0.5)x(1.5)3

3. 3x3/(0.5)x(1.5)3                 4. none of the above

Subtopic:  Kp, Kc & Factors Affecting them |
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The pH of a solution obtained by mixing 100ml of 0.2 M CH3COOH with 100ml of 0.2 M NaOH would be (given pKa for CH3COOH = 4.74)

1. 4.74

2. 8.87

3. 9.10

4. 8.57

Subtopic:  pH calculation |
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If carbon dioxide is 2% dissociated at equilibrium 2CO2 (g)2CO(g) + O2(g). The mole fraction of CO2 at equuilibrium is

1. 1.01/0.98           

2. 0.98/1.01

3. 0.01/0.98           

4. 0.098/1.01

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To a 200 ml of 0.1 M weak acid HA solution 90 ml of 0.1 M solution of NaOH be added, Now, what volume of 0.1 M NaOH be added into above solution so that pH of resulting solution be 5.

[Ka(HA) = 10-5]

1. 2 ml               

2. 20 ml

3. 10 ml             

4. 15 ml

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Calculate the molar solublity of Fe(OH)2 at a pH of 8

[Ksp of Fe(OH)2 = 1.6 X 10-14]

1. 0.06

2. 0.016

3. 0.01

4. 0.16

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The strongest Lewis acid among the following is:

1. BBr3

2. BCl3

3. BF3

4. All are same

Subtopic:  Acids & Bases - Definitions & Classification |
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When a solution of acetic acid was titrated with NaOH, the pH of the solution when half of the acid, neutralised was 4.2. Dissociation constant of the acid is

1. 6.31 × 10-5

2. 3.2 × 10-5

3. 8.7 × 10-8

4. 6.42 × 10-4

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In a nitrating mixture (HNO3 + H2SO4), HNO3 acts as

1. Acid

2. Base

3. Acid as well as Base

4. Neither acid nor base

Subtopic:  Acids & Bases - Definitions & Classification |
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A 20 litre container at 400 K contains CO2(g) at pressure 0.4 atm and an excess of SrO (neglect the volume of solid SrO). The volume of the container is now decreased by moving the movable piston fitted in the container. The maximum volume of the container, when the pressure of CO2 attains its maximum value, when the pressure of C02 attains its maximum value, will be

(Given that: SrCO3(s)  SrO(s) + CO2(g), (Kp =1.6 atm))

(1) 5 L

(2) 10 L

(3) 4L

(4) 2L

Subtopic:  Kp, Kc & Factors Affecting them |
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50 ml of HCl (pH=1) is mixed with another 100 ml of HCl (pH=2) then pH of resulting solution will be approximately

1. 1.2

2. 1.4

3. 1.6

4. 1.8

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