The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol–1. The dissociation constant of acetic acid is :

(\(\mathrm{\Lambda_{H^{+}}^{o} \ = \ 350 \ S \ cm^{2} \ mol^{-1} }\))
(\(\mathrm{\mathrm{\Lambda_{CH_{3}COO^{-}}^{o} \ = \ 50 \ S \ cm^{2} \ mol^{-1} }}\))

1. 1.75×10-5 mol L–1 

2. 2.50×10-5 mol L–1 

3. 1.75×10-4 mol L–1 

4. 2.50×10-4 mol L–1 

Subtopic:   Kohlrausch Law & Cell Constant |
 56%
From NCERT
NEET - 2021
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The molar conductance of NaCl, HCI, and CH3COONa at infinite dilution are 126.45, 426.16, and 91.0 S cm mol–1 respectively. The molar conductance of CH3COOH at infinite dilution will be:

1. 698.28 S cm2 mol–1

2. 540.48 S cm2 mol–1

3. 201.28 S cm2 mol–1

4. 390.71 S cm2 mol–1

Subtopic:   Kohlrausch Law & Cell Constant |
 82%
From NCERT
NEET - 2021
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Consider the following graph of molar conductivity of KCl solution at different concentrations. 

 

The value of limiting molar conductivity for KCl is 150.0 S cmmol-1. The value of the slope at point A will be : 

1. 120 2. 100
3. 110 4. None of the above

Subtopic:   Kohlrausch Law & Cell Constant |
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Consider the following graph.

 

The strong electrolyte in the above graph is represented by:

1. X

2. Y

3. Both X and Y

4. Data given is not sufficient to predict.

Subtopic:  Conductance & Conductivity |
 82%
From NCERT
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The mass of nickel deposited by electrolysis of a solution of Ni(NO3)2 using a current of 5 amperes for 20 min is (atomic mass of Nickle is 58.7) -

1. 2.42 g

2. 1.82 g

3. 3.93 g

4. 6.42 g

Subtopic:  Faraday’s Law of Electrolysis |
 72%
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The value of  ∆G°  in the reaction below would be:
\(\small{\mathrm{Zn}(\mathrm{s})+\mathrm{Ag}_2 \mathrm{O}(\mathrm{s})+\mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{Zn}^{+2}(\mathrm{aq})+2 \mathrm{Ag}(\mathrm{s})+2 \mathrm{OH}^{-}(\mathrm{aq})}\)


Given: \(E_{cell}^{\circ} = 1.04V\)

1. 2.13 kJ

2. 21.3 kJ

3. 213.04 kJ

4. 31.12 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
 75%
From NCERT
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The value of Ecell in the reaction below will be:

\(\small{Pt(s)|Br^{-}(0.010 \ M)|Br_{2}(l) \ ||H^{+}(0.030 \ M)|H_{2}(g)(1 \ bar)|Pt(s)}\)

\(E_{Br^{-}/Br_{2}}^{o} \ = \ -1.09 \ V\)

1. +1.298 V

2. -1.398 V

3. -1.298 V

4. -1.198 V

Subtopic:  Nernst Equation |
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The electricity required in coulombs for the oxidation of 1 mole of FeO to Fe2Ois:

1. 964.87 C 2. 96487 C
3. 96.487 C 4. 9.6487 C
Subtopic:  Faraday’s Law of Electrolysis |
 86%
From NCERT
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The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. The molar conductivity will be -

1. 124 S cm2 mol-1 2. 134 S cm2 mol-1
3. 128 S cm2 mol-1 4. 136 S cm2 mol-1
Subtopic:  Conductance & Conductivity |
 88%
From NCERT
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The incorrect statement(s) among the below is/are:

a. The unit of conductivity is S cm-2
b. Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration.
c. The unit of molar conductivity is S cm2 mol-1
d. Molar conductivity increases with an increase in concentration.

1. a

2. a and d

3. b and d

4. a and c

Subtopic:  Conductance & Conductivity |
 57%
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