The type of inter molecular interactions present in

(a) Methanol and Acetone (i) Van der Waal’s forces of attraction
(b) Acetonitrile and Acetone (ii) ion-dipole interaction
(iii) dipole-dipole interaction
 
(a) (b)
1. (iii) (ii)
2. (ii) (ii)
3. (iii) (iii)
4. (iii) (i)

Subtopic:  Azeotrope |
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The mole fraction of benzene in solution containing 30% by mass in CCl4 is-

1. 0.46

2. 0.64

3. 0.91

4. 0.19

Subtopic:  Concentration Terms & Henry's Law |
 59%
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To make 2.5 kg of 0.25 m aqueous solution, the mass of urea required is-

1. 73 g 2. 37 g
3. 48 g 4. 24 g
Subtopic:  Concentration Terms & Henry's Law |
 78%
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If 1.202 g mL-1 is the density of 20% aqueous Kl , the molarity of the solution is-

1. 2.34 M

2. 1.45 M

3. 3.32 M

4. 0.23 M

Subtopic:  Concentration Terms & Henry's Law |
 73%
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The solubility of H2S in water at STP is 0.195 m. The value of Henry's constant is-

1. 274 atm 2. 285 atm
3. 295 atm 4. 278 atm
Subtopic:  Concentration Terms & Henry's Law |
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A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. The mass percentage of the solvent in resulting solution is:

1. 66.43 %

2. 36.54 %

3. 12.45 %

4. 33.97 %

Subtopic:  Concentration Terms & Henry's Law |
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The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. The composition of the liquid mixture if total vapour pressure is 600 mm Hg is:

1. xA  =0.2 ; xB = 0.8
2. xA = 0.8 ; xB = 0.2
3. xA = 0.4 ; xB = 0.6
4. xA = 0.6 ; xB = 0.4

Subtopic:  Introduction & Colligative properties |
 71%
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The vapour pressure of water in the solution having 50 g of urea dissolved in 850 g of water is-

(Vapor pressure of pure water at 298 K is 23.8 mm Hg) 

1. 23.40 mm of Hg

2. 33.46 mm of Hg

3. 12.76 mm of Hg

4. 87.12 mm of Hg

Subtopic:  Relative Lowering of Vapour Pressure |
 72%
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The amount of sucrose is to be added to 500 g of water such that it boils at 100°C is:

( Given: The boiling point of water at 750 mm Hg is 99.63°C ; Kb = 0.52 K kg mol-1)

1. 145.76 g

2. 213.54 g

3. 121.67 g

4. 195.36 g

 

Subtopic:  Elevation of Boiling Point |
 69%
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The solubility of a gas in a liquid decreases with an increase in temperature because:

1. Dissolution of a gas in a liquid is an endothermic process. 
2. Dissolution of a gas in a liquid is an exothermic process. 
3. Gases are highly compressible.
4. All of the above.
Subtopic:  Introduction & Colligative properties |
 69%
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