Consider the following statements: 

a. Lanthanoid and actinoid belong to the f block and their general electronic configuration is  nf1-14 n-1d0-1ns2 .
b. All lanthanides and actinoids show an oxidation state of +3.
c. The magnetic properties of the actinoids are more complex than those of the lanthanoids. 
d. Lanthanoids are comparatively less electropositive than actinides

Correct statements amongst the above are:

1. a, b 2. c, d, a
3. d, a, b 4. b, c, d

Subtopic:  f-Block Elements- Properties & Uses |
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The correct statement(s) about interstitial compounds is/are:

1. Transition elements are large in size and contain multiple interstitial sites.
2. Transition elements can trap atoms of other elements.
3. Interstitial compounds are chemically inert.
4. All of the above.

Subtopic:  d-Block Elements- Properties & Uses |
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The spin-only magnetic moment of Ce3+ is:
1. 3.25
2. 1.73
3. zero
4. 4.21

Subtopic:  d-Block Elements- Properties & Uses |
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Match the List I with List II:

List I
(Metal ion )
List II
(Number of unpaired electrons)
i. Mn3+ a. 2
ii. Cr3+ b. 4
iii. V3+ c. 1
iv. Ti3+ d. 3

Choose the most appropriate options:
 
i ii iii iv
1. c d b a
2. b d a c
3. d b a c
4. b d c a
Subtopic:  d-Block Elements- Properties & Uses |
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In an aqueous solution, coloured ions would be:

1. Ti3+,V3+, Cu+

2. Sc3+, Mn2+, Fe3+

3. Ti3+,V3+, Mn2+, Fe3+,  Co2+

4. None of the above.

Subtopic:  d-Block Elements- Properties & Uses |
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a. Cr2O72-+H++Fe2+2Cr3++Fe3++H2O
b. Cr2O72-+H++ I-Cr3++H2O+I2
c. H2S+Cr2O72-+H+Cr3++H2O+S

The correct reactions are-

1. a,c

2. b, c

3. a, b

4. a, b, c

 

Subtopic:  Chemistry of Mn and Cr Compounds |
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The correct statement(s) about transition elements are:  

1. +2, and +3 oxidation states are more common for elements in the first transition series, while higher oxidation states are more common for the heavier elements.
2. The heavier transition elements form low-spin complexes only.
3. The atomic sizes of the elements of the first transition series are smaller than those of the heavier elements (elements of 2nd and 3r transition series).
4. All of the above.
Subtopic:  d-Block Elements- Properties & Uses |
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The correct statement regarding inner transition elements is:

1. The general electronic configuration of actinoids is [Xe]54 4f1-145d0-16s2
2. The general electronic configuration of lanthanoids is [Rn]86 5f1-146d0-17s2
3. Alkalies have no action on actinoids.
4. The principal oxidation state of lanthanoids is +1.
Subtopic:  f-Block Elements- Properties & Uses |
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(i) FeCr2O4 + NaOH + O2  ... X.....+ Fe2O3 +H2O
(ii) K2MnO4 +O3 + H2O   .....Y.... + KOH + O2

The products X and Y in the above reactions (i) and (ii) are respectively:

1. Na2Cr2O7 , K2MnO8
2. Na2CrO4, KMnO4
3. Na2Cr2O7, KMnO4
4. NaCrO4, MnO2

Subtopic:  Chemistry of Mn and Cr Compounds |
 65%
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The correct statement(s) about transition elements is/are:  

1. The lowest oxide of a transition metal is basic, the highest is amphoteric/acidic.
2. A transition metal exhibits the highest oxidation state in oxides and fluorides.
3. The highest oxidation state is exhibited in the oxoanions of a metal.
4. All of the above.

Subtopic:  d-Block Elements- Properties & Uses |
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