The value of E0 cell for the following reaction is:
\(Cu^{2+}+ Sn^{2+}\to Cu +Sn^{4+ } \)

(Given, equilibrium constant is 106)

1. 0.17 2. 0.01
3. 0.05 4. 1.77

Subtopic:  Electrode & Electrode Potential |
 73%
From NCERT
AIPMT - 1999
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The standard Emf of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 25 ºC. The equilibrium constant of the reaction would be:

(Given F = 96500 C mol–1; R = 8.314 J K–1 mol–1

1. 4.0 × 1012

2. 1.0 × 102

3. 1.0 × 1010

4. 2.0 × 1011

Subtopic:  Relation between Emf, G, Kc & pH |
 75%
From NCERT
AIPMT - 2004
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In the silver plating of copper, K[Ag(CN)2] is used instead of AgNO3. The reason is:
 

1. A thin layer of Ag is formed on Cu
2. More voltage is required
3. Ag+ ions are completely removed from the solution
4. Less availability of Ag+ ions, as Cu can not displace Ag from [Ag(CN)2] ion
Subtopic:  Electrochemical Series |
 61%
AIPMT - 2002
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On the basis of the information available from the reaction:

43Al+O223Al2O3, G=-827 KJ mol-1

The minimum e.m.f. required to carry out the electrolysis of Al2O3 is:
(F = 96500 C mol–1)

1. 2.14 V

2. 4.28 V

3. 6.42 V

4. 8.56 V

Subtopic:  Electrode & Electrode Potential |
 66%
From NCERT
AIPMT - 2003
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The EMF of a Daniel cell at 298 K is E Zn|ZnSO4(0.01 M) || CuSO4(1.0 M)|Cu.
When the concentration of ZnSO4 is 1.0 M and that of CuSO4 is 0.01 M, the EMF is changed to E2. The correct relationship between E1 and E2 is:

1. E1 > E2 2. E1 < E2
3. E1 = E2 4. E2 = 0 ≠ E1
Subtopic:  Electrode & Electrode Potential |
 79%
From NCERT
AIPMT - 2003
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The following metals should be arranged so that they push one another out of the salt solution in that order: 

Al, Cu, Fe, Mg, and Zn.
 

1. Cu <Fe<Zn< Al< Mg

2. Zn< Fe< Cu< Mg< Al

3. Mg<Cu <Zn <Fe< Al

4. Al<Zn<Fe< Cu< Mg

Subtopic:  Electrode & Electrode Potential |
 67%
From NCERT
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The correct increasing order of reducing power of the metals is:

K+/K = –2.93 V
Ag+/Ag = 0.80 V
Hg2+/Hg = 0.79 V
Mg2+/Mg = –2.37 V
Cr3+/Cr = – 0.74 V
 
1. Cr<Mg<K<Ag<Hg 2. Mg<K<Ag<Hg<Cr
3. K<Ag<Hg<Cr<Mg 4. Ag<Hg<Cr<Mg<K

Subtopic:  Electrode & Electrode Potential |
 85%
From NCERT
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The correct statement about the given galvanic cell equation is -

Zn(s) + 2Ag+­­­(aq) → Zn2+(aq) + 2Ag(s)

1. The current will flow from silver to zinc in the external circuit.
2. The current will flow from zinc to silver in the external circuit.
3. The current will flow from silver to zinc in the internal circuit.
4. The current will flow from zinc to silver in the internal circuit.

Subtopic:  Electrolytic & Electrochemical Cell |
 61%
From NCERT
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 2Cr(s) + 3Cd2+(aq)  2Cr3+(aq) + 3Cd

ECr3+/Cr= -0.74 VECd2+/Cd=-0.40 V

The value of Gro in the above reaction will be-

1. -196.83 kJ

2. 196.83 kJ

3. 186.83 kJ

4. -186.83 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
 74%
From NCERT
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The incorrect statement(s) among the below is/are:

a. The unit of conductivity is S cm-2
b. Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration.
c. The unit of molar conductivity is S cm2 mol-1
d. Molar conductivity increases with an increase in concentration.

1. a

2. a and d

3. b and d

4. a and c

Subtopic:  Conductance & Conductivity |
 57%
From NCERT
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