The rate of the reaction
2NO + Cl2 → 2NOCl is given by the rate equation
rate = k[NO]2[Cl2]
The value of the rate constant can be increased by:
1. Increasing the concentration of NO
2. Increasing the concentration of Cl2
3. Increasing the temperature
4. All of the above
Activation energy and rate constant (k1 and k2) of a chemical reaction at two different temperatures (T1 and T2) are related by:
1. | \(\ln \frac{k_2}{k_1}=-\frac{E_a}{R}\left(\frac{1}{T_2}-\frac{1}{T_1}\right)\) |
2. | \(\ln \frac{k_2}{k_1}=-\frac{E_a}{R}\left(\frac{1}{T_2}+\frac{1}{T_1}\right)\) |
3. | \(\ln \frac{k_2}{k_1}=\frac{E_a}{R}\left(\frac{1}{T_2}-\frac{1}{T_1}\right)\) |
4. | \(\ln \frac{k_2}{k_1}=-\frac{E_a}{R}\left(\frac{1}{T_1}-\frac{1}{T_2}\right)\) |
The rate of the reaction can be written in three ways:
The relationship between k and k′ and between
k and k′′ are-
1. k′ = k, k′′= k
2. k′= 2k; k′′= k
3. k′= 2k, k′′= k/2
4. k′ = 2k; k′′= 2k
The half-life of a certain enzyme catalysed reaction is 138 s, that follow the 1st order kinetics. The time required for the concentration of the substance to fall from 1.28 mg L–1 to 0.04 mg L–1, is:
1. 276 s
2. 414 s
3. 552 s
4. 690 s
The unit of rate constant for a zero-order reaction is:
1.
2.
3.
4.
A 300-gram radioactive sample has a half-life of 3 hours. After 18 hours the remaining quantity will be:
1. 4.68 gram
2. 2.34 gram
3. 3.34 gram
4. 9.37 gram
If the concentration of a solution is changed from 0.2 to 0.4, then what will be rate and rate constant. The reaction is of first order and rate constant is :
1.
2.
3.
4.
Half-life of a radioactive sample is 4 days. After 16 days what quantity of matter remains undecayed?
1.
2.
3.
4.
The rate of a first-order reaction is 1.5 ×10–2 mol L–1 min–1 at 0.5 M concentration of the reactant. The half-life of the reaction is:
1. | 23.1 min | 2. | 8.73 min |
3. | 7.53 min | 4. | 0.383 min |
If the bombardment of α-particle on \(N_{7}^{14}\) emits protons, then new atom will be:
1. \(O_{8}^{17}\)
2. \(O_{8}^{16}\)
3. \(C_{6}^{14}\)
4. Ne