The following two reactions are knownFe2O3(s)+3CO(g)2Fe(s)+3CO2(g);
H=-26.88 kJ
FeO(s)+CO(g)Fe(s)+CO2(g);
H=-16.5 kJ

The value of H for the following reaction

Fe2O3(s)+CO(g)2FeO(s)+CO2(g) is:

1. -43.3 kJ

2. -10.3 kJ

3. +6.2 kJ

4. +10.3 kJ

Subtopic:  Enthalpy & Internal energy |
 76%
From NCERT
AIPMT - 2010
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Match List – I (Equations) with List – II (Type of processes) and select the correct option.

List – I List – II
Equation  Type of processes
(a) Kp > Q  (i) Non-spontaneous
(b) ∆Gº < RT ln Q  (ii) Equilibrium
(c) Kp = Q  (iii) Spontaneous and endothermic
(d) T > \(\frac{\Delta H}{\Delta S}\) (iv) Spontaneous
 
Options: (a) (b) (c) (d)
1. (iii) (iv) (ii) (i)
2. (iv) (i) (ii) (iii)
3. (ii) (i) (iv) (iii)
4. (i) (ii) (iii) (iv)
Subtopic:  Spontaneity & Entropy | Gibbs Energy Change |
 63%
From NCERT
AIPMT - 2010
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Equal volumes of two monoatomic gases, A and B, at same temperature and pressure are mixed. The ratio of specific heats (Cp/Cv) of the mixture will be:
1.  1.50
2.  3.3
3.  1.67
4.  0.83

Subtopic:  Cp & Cv |
 78%
AIPMT - 2012
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Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be:

1. 3 Joules

2. 9 Joules

3. Zero

4. Infinite

Subtopic:  First Law of Thermodynamics |
 90%
From NCERT
AIPMT - 2010
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For vaporization of water at 1 atmospheric pressure, the values of ∆H and ∆S are 40.63 kJ mol–1 and 108.8 JK–1 mol–1, respectively. The temperature when Gibbs energy change (∆G) for this transformation will be zero, is:

1. 393.4 K

2. 373.4 K

3. 293.4 K

4. 273.4 K

Subtopic:  Gibbs Energy Change |
 78%
From NCERT
AIPMT - 2010
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Consider the following processes:

                                       ∆H (kJ/mol)
½ A → B                            + 150
3B → 2C + D                      –125
E + A → 2D                        +350

For B + D → E + 2C, ∆H will be-

1. 325 kJ/mol 

2. 525 kJ/mol

3. –175 kJ.mol 

4. –325 kJ/mol

Subtopic:  Enthalpy & Internal energy |
 72%
From NCERT
AIPMT - 2011
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One mole of an ideal gas at 300 K is expanded isothermally from an initial volume of 1 litre to 10 litres. The ∆E for this process is:
(R = 2 cal. mol-1K-1)
1. 1381.1 cal.
2. Zero
3. 163.7 cal.
4. 9 lit. atm

Subtopic:  First Law of Thermodynamics |
 82%
From NCERT
AIPMT - 1998
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If the bond energies of H–H, Br – Br, and H –Br are 433, 192, and 364 kJ mol–1 respectively, the ∆Hº for the reaction H2(g) + Br2(g) → 2HBr(g) will be:

1. +103 kJ

2. +261kJ

3. –103 kJ

4. –261 kJ 

Subtopic:  Thermochemistry |
 73%
From NCERT
AIPMT - 2004
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If a system is expanded under adiabatic process, then:

1.  Temperature increases
2.  ∆E decreases
3.  ∆E increases
4.  None of the above

Subtopic:  Enthalpy & Internal energy |
 61%
From NCERT
AIPMT - 1999
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Which of the following is true for a reaction in which all the reactants & products are liquids:
1.  ∆H = ∆E
2.  ∆H = ∆W
3.  ∆H > ∆E
4.  None of the above

Subtopic:  Enthalpy & Internal energy |
 82%
From NCERT
AIPMT - 1999
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