Select the correct option based on statements below:
Assertion (A): | It is difficult to replace chlorine with -OH in chlorobenzene in comparison to that in chloroethane. |
Reason (R): | Chlorine carbon (—Cl) bond in chlorobenzene has a partial double bond character due to resonance. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Sulphuric acid is not used during the reaction of alcohols with KI and acts as :
1. Reducing agent
2. Electron donor
3. Electron acceptor
4. Oxidising agent
How many dihalogen derivatives of propane are there?
1. | 1 | 2. | 2 |
3. | 3 | 4. | 4 |
PCl5 reacts with propanone, to give:
1. gem dichloride
2. vic dichloride
3. propanal
4. propane chloride
Select the correct option based on statements below:
Assertion (A): | The presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution. |
Reason (R): | The nitro group, being an electron-withdrawing group, decreases the electron density over the benzene ring. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | KCN reacts with methyl chloride to give methyl isocyanide. |
Reason (R): | \(CN^-\) is an ambident nucleophile. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Select the correct option based on statements below:
Assertion (A): | The boiling points of alkyl halides decrease in the order RI> RBr > RCl > RF |
Reason (R): | The boiling points of alkyl chlorides, bromides, and iodides are considerably higher than those of the hydrocarbons of comparable molecular mass. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Select the correct option based on statements below:
Assertion (A): | Phosphorus chlorides (tri and Penta) are preferred over thionyl chloride for the preparation of alkyl chlorides from alcohols. |
Reason (R): | Phosphorus chlorides give pure alkyl halides. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
The correct match of column I (Reactions) with column II (Name of reactions) is:
Column I | Column II | ||
A. | 1. | Fittig reaction | |
B. | 2. | Wurtz-Fittig reaction | |
C. | 3. | Finkelstein reaction | |
D. | \(\begin{aligned}\small{C_{2}H_{5}Cl \ + \ NaI \ \xrightarrow[]{\textbf{dry acetone}} \\ \ C_{2}H_{5}I \ + \ NaCl} \end{aligned}\) | 4. | Sandmeyer reaction |
Codes
A | B | C | D | |
1. | 2 | 1 | 4 | 3 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 1 | 3 | 2 |
Match the reactions given in Column I with the types of reactions given in Column II and mark the appropriate option.
Column I | Column II | ||
A. | |
1. | Nucleophilic aromatic substitution reaction |
B. | |
2. | Electrophilic aromatic substitution |
C. | |
3. | Saytzeff elimination |
D | 4. | Electrophilic addition |
|
5. | Nucleophilic substitution reaction |
Codes
A | B | C | D | |
1. | 2 | 4 | 5 | 1 |
2. | 3 | 1 | 5 | 2 |
3. | 5 | 4 | 3 | 2 |
4. | 4 | 5 | 3 | 2 |