\(\Lambda _{m(NH_{4}OH)}^{o}\) is equal to -
1. \(\Lambda _{m(NH_{4}OH)}^{o} \ + \ \Lambda _{m(NH_{4}Cl)}^{o} \ - \ \Lambda _{m(HCl)}^{o}\)
2. \(\Lambda _{m(NH_{4}Cl)}^{o} \ + \ \Lambda _{m(NaOH)}^{o} \ - \ \Lambda _{m(NaCl)}^{o}\)
3. \(\Lambda _{m(NH_{4}Cl)}^{o} \ + \ \Lambda _{m(NaCl)}^{o} \ - \ \Lambda _{m(NaOH)}^{o}\)
4. \(\ \Lambda _{m(NaOH)}^{o} \ + \ \Lambda _{m(NaCl)}^{o}\ - \ \Lambda _{m(NH_{4}Cl)}^{o}\)
The half-cell reaction at the anode during the electrolysis of aqueous sodium chloride solution is represented by :
1. Na+(aq) + e- ⟶ Na(s) ; \(E_{cell}^{o} \ = \ -2.71 \ V \)
2. 2H2O(l) ⟶ O2(g) + 4H+(aq) + 4e- ; \(E_{cell}^{o} \) = 1.23 V
3. H+(aq) + e- ⟶ \(\frac{1}{2}\)H2(g) ; \(E_{cell}^{o} \) = 0.00 V
4. Cl-(aq) ⟶ \(\frac{1}{2}\)Cl2(g) + e- ; \(E_{cell}^{o}\)
Match the terms given in Column I with the items given in Column II.
Column I |
Column II |
A. B. Eocell C. D. Gcell |
1. Intensive property 2. Depends on number of ions/volume 3. Extensive property 4. Increases with dilution |
Codes
Options: | A | B | C | D |
1. | 2 | 3 | 4 | 1 |
2. | 1 | 2 | 3 | 5 |
3. | 5 | 4 | 3 | 2 |
4. | 4 | 1 | 2 | 3 |
Given below are two statements:
Assertion (A): | Current stops flowing when Ecell = 0. |
Reason (R): | Equilibrium of the cell reaction is attained. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | Copper sulphate can be stored in a zinc vessel. |
Reason (R): | Zinc is less reactive than copper. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
The correct statement about charging of the lead storage battery is:
1. PbSO4 anode is reduced to Pb.
2. PbSO4 cathode is reduced to Pb.
3. PbSO4 cathode is oxidised to Pb.
4. PbSO4 anode is oxidised to PbO2.
The cell constant of a conductivity cell-
1. | Changes with the change of electrolyte. |
2. | Changes with the change of concentration of electrolyte. |
3. | Changes with the temperature of the electrolyte. |
4. | Remains constant for a cell. |
The quantity of charge required to obtain one mole of aluminium from Al2O3 is :
1. 1 F
2. 6 F
3. 3 F
4. 2 F
The most stable oxidized species among the following is:
\(E_{{\mathrm{Cr}_2 \mathrm{O}_7^2}/ \mathrm{Cr}^{3+}}^{o} =1.33 \mathrm{~V} ; E_{\mathrm{Cl}_2 / \mathrm{Cl}^{-}}^{o}=1.36 \mathrm{~V} \)
\( E_{\mathrm{MnO_{4}}^{-} / \mathrm{Mn}^{2+}}^{o}=1.51 \mathrm{~V} ; E_{\mathrm{Cr}^{3+} / \mathrm{Cr}}^{o}=-0.74 \mathrm{~V}\)
1. | Cr3+ | 2. | MnO4- |
3. | Cr2O72- | 4. | Mn2+ |
The incorrect statement about the solution of electrolytes is:
1. | Conductivity of solution depends upon the size of ions. |
2. | Conductivity depends upon the viscosity of solution. |
3. | Conductivity does not depend upon the solvation of ions present in solution. |
4. | Conductivity of solution increases with temperature. |