A brown ring formed in the ring test for NO3- ion is due to the formation of:
1. [Fe(H2O)5(NO)]2+
2. FeSO4.NO2
3. [Fe(H2O)4(NO)2]2+
4. FeSO4.HNO3

Subtopic:  Group 15 - Preparation, Properties & Uses |
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Bismuth is present in a +5 oxidation state in: 

1. \(\mathrm{Bi}_{2} \mathrm{O}_{5}\)
2. \(\mathrm{BiF}_{5}\)
3. \(\mathrm{BiCl}_{5}\)
4. \(\mathrm{Bi}_{2} \mathrm{~S}_{5}\)

Subtopic:  Group 15 - Preparation, Properties & Uses |
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Ammonium dichromate and barium azide on heating gives: 

1. N2 in both cases.
2. N2 with ammonium dichromate and  NO with barium azide.
3. N2O with ammonium dichromate and  N2 with barium azide.
4. N2O with ammonium dichromate and  NO2 with barium azide.

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The number of  moles of NO produced by the oxidation of two moles of NH3 will be -

1. 2

2. 3

3. 4

4. 6

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The oxidation state of the central atom in the anion of compound \(\mathrm{NaH}_2 \mathrm{PO}_2\) will be:

1. +3 2. +5
3. +1 4. -3
Subtopic:  Group 15 - Preparation, Properties & Uses |
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A compound that does not have a tetrahedral shape is:

1. \(\mathrm{NH}_{4}^{+}\)
2. \(\mathrm{SiCl}_{4}\)
3. \(\mathrm{SF}_{4}\)
4. \(\mathrm{SO}_{4}^{2-}\)

Subtopic:  Group 16 - Preparation, Properties & Uses |
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Which of the following are peroxoacids of sulphur?
1. \(\mathrm{H}_{2} \mathrm{SO}_{5} \text { and } \mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{8}\)
2. \(\mathrm{H}_{2} \mathrm{SO}_{5} \text { and } \mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{7}\)
3. \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{7} \text { and } \mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{8}\)
4. \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{6} \text { and } \mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{7}\)

Subtopic:  Group 16 - Preparation, Properties & Uses |
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In the preparation of compounds of Xe, Bartlett had taken \(O_{2}^{+}PtF_{6}^{-}\) as a base compound. This is because: 

1. Both O2 and Xe have same size.

2. Both O2 and Xe have same electron gain enthalpy.

3. Both O2 and Xe have almost same ionisation enthalpy.

4. Both Xe and O2 are gases.

Subtopic:  Group 18 - Preparation, Properties & Uses |
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Which of the following is true regarding the P4 molecule of white phosphorus?

1. It has 6 lone pairs of electrons.

2. It has four P — P single bonds.

3. It has three P — P single bonds.

4. It has four lone pairs of electrons.

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The correct statement among the following about SO2 gas is:   

1. It acts as bleaching agent in moist conditions.
2. It's molecule has linear geometry.
3. It's concentrated solution is used as a disinfectant.
4. It can be prepared by the reaction of dilute H2SOwith metal sulphide.

Subtopic:  Group 16 - Preparation, Properties & Uses |
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