The number of sigma ($\mathrm{\sigma }$) and pi ($\mathrm{\pi }$) bonds in pent-2-en-4-yne is:

1.  13 $\mathrm{\sigma }$ bonds and no $\mathrm{\pi }$ bond.

2.  10 $\mathrm{\sigma }$ bonds and 3 $\mathrm{\pi }$ bonds.

3.  8 $\mathrm{\sigma }$ bonds and 5 $\mathrm{\pi }$ bonds.

4.  11 $\mathrm{\sigma }$ bonds and 2 $\mathrm{\pi }$ bonds.

Xe F${}_2$ is isostructural with : 

1. ${\mathrm{SbCl}}_3$

2. ${\mathrm{BCl}}_3$

3. ${\mathrm{TeF}}_2$

4. ${\mathrm{ICl}}_2^{-}$

Match the following:

Which of the following is the correct option?

The electronic configurations of the elements A, B, and C are given below.

$\mathrm{A}<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>=<mspace\; width="1em"></mspace>1{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>2{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>2{\mathrm{p}}^6$
$\mathrm{B}<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>=<mspace\; width="1em"></mspace>1{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>2{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>2{\mathrm{p}}^6<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>3{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>3{\mathrm{p}}^3$
$\mathrm{C}<mspace\; width="1em"></mspace>=<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>1{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>2{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>2{\mathrm{p}}^6<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>3{\mathrm{s}}^2<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>3{\mathrm{p}}^5$

The stable form of A may be represented by the formula:

Which of the compounds given below will exhibit a linear structure?

A diatomic molecule AB has a dipole moment of 0.816 debye. If its bond length is 100 pm. then what percentage of an electronic charge will exist on each atom?

1. 83%

2. 37%

3. 10%

4. 17%

The correct order of increasing dipole moment is : 

1. ${\mathrm{CF}}_4$ < ${\mathrm{NH}}_3$ < ${\mathrm{NF}}_3$ < ${\mathrm{H}}_2\mathrm{O}$

2. ${\mathrm{CF}}_4$ < ${\mathrm{NH}}_3$ < ${\mathrm{H}}_2\mathrm{O}$ < ${\mathrm{NF}}_3$

3. ${\mathrm{CF}}_4$< ${\mathrm{NF}}_3$ < ${\mathrm{H}}_2\mathrm{O}$ < ${\mathrm{NH}}_3$

4. ${\mathrm{CF}}_4$< ${\mathrm{NF}}_3$< ${\mathrm{NH}}_3$ < ${\mathrm{H}}_2\mathrm{O}$ 

Which of the following molecules have unequal bonds?

1. $Cl{F}_3$

2. $B{F}_3$

3. $Al{F}_3$

4. $N{F}_3$

Decreasing order of stability of ${\mathrm{O}}_2,{\mathrm{O}}_2^{-},{\mathrm{O}}_2^{+}<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{O}}_2^{2-}$is:

1. $O_2^{+}>O_2>O_2^{-}>O_2^{2-}$

2. $O_2^{2-}>O_2^{-}>O_2>O_2^{+}$

3. $O_2>O_2^{+}>O_2^{2-}>O_2^{-}$

4. $O_2^{-}>O_2^{2-}>O_2^{+}>O_2$

Compound in which central atom assumes sp³d hybridisation is

1. SO₃

2. PCl₅

3. SO₂

4. PCl₃