The electrode potential of Cu electrode dipped in 0.025 M CuSO4 solution at 298 K is:

(standard reduction potential of Cu = 0.34 V)

1. 0.047 V

2. 0.293 V

3. 0.35 V

4. 0.387 V

Subtopic:  Nernst Equation |
 61%
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\(Cu(s)|Cu^{+2}(10^{-3} \ M) \ || \ Ag^{+}(10^{-5} \ M)|Ag(s)\)
if \(E_{Cu^{+2}/Cu}^{o} \ = \ +0.34 \ V\), and \(E_{Ag^{+}/Ag}^{o} \ = \ +0.80 \ V\)
Ecell will be: 

1. 0.46 V
2. \(0.46-\frac{RT}{2F}ln10^{7}\)
3. \(0.46+\frac{RT}{2F}ln10^{7}\)
4. \(0.46-\frac{RT}{2F}ln10^{2}\)

Subtopic:  Nernst Equation |
 52%
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Consider the following cell reaction 

2Fe(s) + O2(g) + 4H+(aq)  2Fe2+(aq) + 2H2O(l)

E° = 1.67 V, At [Fe2+] = 10-3 M, PO2 = 0.1 atm and pH = 3, the cell potential at 25 °C is : 

1. 1.27 V

2. 1.77 V

3. 1.87 V

4. 1.57 V

Subtopic:  Nernst Equation |
 56%
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The specific conductivity of a saturated solution of KI3 is 4.59 × 10-6 ohm-1 cm-1 and it's molar conductance is 1.53 ohm-1 cm2 mol-1. The Ksp Of KI3 will be : 

1. 4 x 10-12

2. 27 x 27 x 10-9

3. 9 x 10-6

4. 4 x 10-6

Subtopic:  Conductance & Conductivity |
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A 100.0 mL dilute solution of Ag+ is electrolyzed for 15.0 minutes with a current of 1.25 mA and the silver is removed completely. The initial [Ag+] is :-

1. 2.32 x 10-1 M

2. 2.32 x 10-4 M

3. 2.32 x 10-5 M

4. 1.17 x 10-4 M

Subtopic:  Faraday’s Law of Electrolysis |
 63%
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The amount of charge required for the oxidation of 1 mol of H2O2 to O2 is: 

1. 9.65×104 C

2. 93000 C

3. 1.93×105 C

3. 19.3 × 10C

Subtopic:  Faraday’s Law of Electrolysis |
 65%
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The number of Faradays (F) required to produce 20 g of calcium from molten CaCl2 (Atomic mass of Ca=40 g mol-1) is:

1. 2

2. 3

3. 4

4. 1

Subtopic:  Faraday’s Law of Electrolysis |
 67%
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On electrolysis of dilute sulphuric acid using Platinum (Pt) electrode, the product obtained at the anode will be:

1. Oxygen gas

2. H2S gas

3. SO2 gas

4. Hydrogen gas 

Subtopic:  Electrolytic & Electrochemical Cell |
 64%
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A fuel cell develops an electrical potential from the combustion of butane at 1 bar and 298 K 

C4H10(g) + 6.5O2(g) → 4 CO2(g) + 5H2O(l); E of a cell is: 

(Given Go =-2746 kJ/mole )

1. 4.74 V

2. 0.547 V

3. 4.37 V

4. 1.09 V

Subtopic:  Relation between Emf, G, Kc & pH |
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A gas X at 1 atm is bubbled through a solution containing a mixture of 1 M Yand 1 M Z- at 25 oC . If the reduction potential of Z > Y > X, then:

1. Y will oxidize X but not Z.  2. Y will oxidize Z but not X.
3. Y will oxidize both X and Z.  4. Y will reduce both X and Z.

Subtopic:  Electrode & Electrode Potential |
 68%
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