The molecule among the following having the highest reactivity toward the SN1 reaction is:

1. C6H5CH(C6H5)Br

2. C6H5CH(CH3)Br

3. C6H5C(CH3)(C6H5)Br

4. C6H5CH2Br

Subtopic:  Nucleophile & Electrophile |
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A: Inductive effect is a permanent effect.

R: -CH3 group shows +l effect.

1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion

3. Assertion is a true statement but Reason is false.

4. Both Assertion and Reason are false statements.

 

Subtopic:  Electron Displacement Effects |
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A: Resonating structures should have the same number of unpaired electrons.

R: The energy content of all resonating structures is the same.

1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

3. Assertion is a true statement but Reason is false.

4. Both Assertion and Reason are false statements.

Subtopic:  Electron Displacement Effects |
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A: Cyclopentadienyl anion is much more stable than allyl anion.

R: Cyclopentadienyl anion is aromatic while allyl anion is only resonance stabilized.

1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

3. Assertion is a true statement but Reason is false.

4. Both Assertion and Reason are false statements.

 

Subtopic:  Aromaticity & Polarity |
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A: Benzene and naphthalene are aromatic hydrocarbons.

R: Benzene and naphthalene contain the same number of delocalized π electrons.

1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

3. Assertion is a true statement but Reason is false.

4. Both Assertion and Reason are false statements, then mark (4).

 

Subtopic:  Aromaticity & Polarity |
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A: Alkyl groups show +l effect.

R: Halogens are -l and +R groups.

1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

3. Assertion is a true statement but Reason is false.

4. Both Assertion and Reason are false statements.

 

Subtopic:  Electron Displacement Effects |
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A:  is the most stable alkene due to 12-α hydrogen atoms

R: 'H' is more electronegative than carbon.

1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion

3. Assertion is a true statement but Reason is false.

4. Both Assertion and Reason are false statements. 

 

Subtopic:  Electron Displacement Effects |
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A: A compound having a non-superimposable mirror image is optically active.

R: Optically active compound must contain chiral carbon.

1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

3. Assertion is a true statement but Reason is false

4. Both Assertion and Reason are false statements.

 

Subtopic:  Stereo Isomers |
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Which of the following compounds is isomeric with methyl vinyl ether?

1. Propanal

2. 1-propanol

3. Ethyl methyl ether

4. Dimethylether

Subtopic:  Structural Isomers |
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The number of chiral centers present in 3,4-dibromo-2-pentanol is/are :

1. 1

2. 2

3. 3

4. 4

Subtopic:  Stereo Isomers |
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