Which of the following colligative properties is associated with the concentration term 'molarity'?

(1) Lowering of vap.pressure

(2) Osmotic pressure

(3) Depression in freezing point

(4) Elevation in boiling point

Amongst the following identify the species with an atom in (+6) oxidation state.

1. Mn${\mathrm{O}}_4^{-}$

2. Cr$(\mathrm{CN}{)}_{}^{3-}6$

3. Ni${\mathrm{F}}_6^{2-}$

4. CrO₂Cl₂

A metallic oxide contains 20% oxygen. The equivalent weight of metal is

1. 12

2. 16

3. 32

4. 64

Which one is correct about CH₂ = CCl₂?

(1) Both carbon are in +2 oxidation state.

(2)  Both carbon are in +- oxidation state.

(3) Once carbon has +2 and other -2 oxidation state.

(4) The average oxidation number of carbon is +1.

What is the equivalent weight of H₃PO₃ in the following disproportionation reaction:-

H₃PO₃ $\to$H₃PO₄ + PH₃

1. $\frac{M}{6}$   

 2. $\frac{M}{2}$ 

3.  $\frac{2M}{3}$ 

 4. $\frac{M}{3}$

25.0 g of FeSO₄.7H₂O was dissolved in water containing dilute H₂SO₄, and the volume was made up to 1.0 L. 25.0 mL of this solution required 20 mL of an N/10 KMnO₄ solution for complete oxidation. The percentage of FeSO₄^. 7H₂O in the acid solution is

(1) 78%

(2) 98%

(3) 89%

(4) 79%

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

(1) HOCl<HOClO<HOClO₂<HOClO₃

(2) HOClO<HOCl<HOClO₃<HOClO₂

(3) HOClO₂<HOClO₃<HOClO<HOCl

(4) HOClO₃>HOClO₂<HOClO<HOCl

The valency of Cr in the complex [Cr(H₂O)₄Cl₂]⁺ [MP PMT 2000]

(1) 1

(2) 3

(3) 5

(4) 6

Oxidation number of cobalt in K[Co(CO)₄] is

(1) + 1

(2) + 3

(3) – 1

(4) – 3

The oxidation number of phosphorus in Ba(H₂PO₂)₂ is [Kurukshetra CEE 1998; DCE 2004]

(1) – 1

(2) + 1

(3) + 2

(4) + 3