In a chemical change from ${\mathrm{PCl}}_3 \stackrel{ }{\to }{\mathrm{PCl}}_5$ the hybrid state of P changes from:

(1) sp² to sp³

(2) sp³ to sp²

(3) sp³ to sp³d

(4) sp³ to dsp

In which case observed dipole moment is greater than theoretical dipole moment?

1.

2.

3.

4.

Amongst ${\mathrm{H}}_2\mathrm{O}, {\mathrm{H}}_2\mathrm{S}, {\mathrm{H}}_2\mathrm{Se} \mathrm{and} {\mathrm{H}}_2\mathrm{Te}$ the one with the highest boiling point is:

1. H₂O because of H-bonding.

2. H₂Te because of higher molecular weight.

3. H₂S because of H-bonding.

4. H₂Se because of lower molecular weight.

Which of the following species contains an equal number of $\mathrm{\sigma }$ and $\mathrm{\pi }$ bonds?

(a) ${\mathrm{HCO}}_3^{-}$                                    (b) XeO₄

(c) (CN)₂                                      (d) CH₂(CN)₂

Which one of he following pairs is isostructural (i.e., having the same shape and hybridization)?
(a) [BCl₃ and BrCl₃]

(b) [NH₃ and ${\mathrm{NO}}_3^{-}$]

(c) [NF₃ and BF₃]

(d) [${\mathrm{BF}}_4^{-}$ and ${\mathrm{NH}}_4^{+}$]

Bond order of 1.5 is shown by

(a) ${\mathrm{O}}_2^{+}$     

(b) ${\mathrm{O}}_2^{-}$       

(c) ${\mathrm{O}}_2^{2-}$     

(d) O₂

What is the dominant intermolecular force on bond that must be overcome in converting liquid CH₃OH to a gas?

(a) Hydrogen bonding

(b) Dipole-dipole interaction

(c) Covalent bonds

(d) London dispersion force

The correct order of electronegativity of hybrid orbitals of carbon is:

1. sp > sp² < sp³             

2. sp > sp² > sp³

3. sp < sp² > sp³             

4. sp < sp² < sp³

${\mathrm{H}}_2\mathrm{O}$ has a net dipole moment while
\(BeF_2\) has zero dipole moment because :

1. F is more electronegative than oxygen.

2. Be is more electronegative than oxygen. 

3. ${\mathrm{H}}_2\mathrm{O}$ $$ molecule is linear and \(BeF_2\) is bent.

4. ${\mathrm{BeF}}_2$ molecule is linear and ${\mathrm{H}}_2\mathrm{O}$ is bent.

Which of the following compound have the same no. of lone pair on their central atom?

(a)${\mathrm{XeF}}_5^{- }$             (b) ${\mathrm{BrF}}_3$                 (c) ${\mathrm{XeF}}_2$                     (d) ${\mathrm{H}}_3{\mathrm{S}}^{+}$               

(e) Triple Methylene     

options are as follows :        

(a) (iv) and (v)                                     (b) (i) and (iii) 

(c) (i) and (ii)                                       (d) (ii) (iv), (v)