An ionic compound has a unit cell consisting of A ions at the corners of a cube and B ions on the centers of the faces of the cube. The empirical formula for this compound would be :
1. AB
2. A2B
3. AB3
4. A3B
The formula of nickel oxide with metal deficiency defect in its crystal is . The crystal contains ions. The fraction of nickel existing as ions in the crystal is-
1. 0.96
2. 0.04
3. 0.50
4. 0.31
The edge length of fcc unit cell of NaCl is 508 pm.
If the radius of cation is 110 pm then radius of the anion is :
1. 244 pm
2. 144 pm
3. 288 pm
4. 398 pm
An element occurring in the bcc structure has unit cells. The total number of atoms of the element in these cells will be:
1.
2.
3.
4.
A compound that shows Schottky as well as Frenkel defect among the following is -
1. ZnS
2. AgBr
3. NaCl
4. AgCl
If an element (at. Wt. = 50) crystallises in fcc lattice, with a = 0.50 nm, then the density of unit cell if it contains 0.25 % Schottky defect is -
(Use )
1. 2.0 g/cc
2. 2.66 g/cc
3. 3.06 g/cc
4. None of the above.
In the spinel structrue, oxides ions are cubical-closest packed whereas 1/8th of tetrahedral voids are occupied by cation and 1/2 of octahedral voids are occupied by cations. The general formula of the compound having spinel structure is :
1.
2.
3.
4.
An element has a body-centered cubic (BCC) structure with a cell edge of 288 pm. The atomic radius is:
1. pm
2. pm
3. pm
4. pm
Select the correct option based on statements below:
Assertion (A): | Due to Frenkel defect, the density of the crystalline solid decreases. |
Reason (R): | In Frenkel defect cation and anion leave the crystal. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
The crystal with a metal deficiency defect is -
1. NaCl
2. FeO
3. ZnO
4. KCl