Doubt by Maria

Which of the following are true about the metal EDTA complex if it is a 3D series metal a )the ratio of the most of metal and EDTA is 1:6 b) the ratio of the moles of metal and ETDA is 6:1 c) the ratio of the moles of metals and EDTA is 1:1 D) the 3D metal does not form Bond with EDTA. Pls explain the answer.

Answers

Answer by Rishikant Pandey

The ratio of Cu to EDTA is the number of copper ions per EDTA ion. In this case there is one EDTA ion for every copper ion so the ratio is 1:1.

Copper bonds with six electron pairs on EDTA to form the complex shown below where the central metal species is copper(II):

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EDTA4− usually binds to a metal cation through its two amines and four carboxylates. Many of the resulting coordination compounds adopt octahedral geometry. Many complexes of EDTA4− adopt more complex structures due to either the formation of an additional bond to water, i.e. seven-coordinate complexes, or the displacement of one carboxylate arm by water. The Fe(III) complex of EDTA is seven-coordinate.
The scenario that in the presence of an excess EDTA, metals can bind to more than one EDTA molecules does not exist. The problem stems from the fact that the complex is weakened upon incorporating another molecule of EDTA. The optimal strength of the complex is when EDTA and the metal adopt octahedral geometry.
 
 
 
The unusual property of EDTA is its ability to chelate or complex metal ions in 1:1 metal-to-EDTA complexes. 
answer (c) the ratio of moles of metal and edta is 1:1

Answer by ABHISHEK BISHT

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