A compound A of formula C3H6Cl2 on reaction with alkali can give B of formula C3H6O or C of formula C3H4. B on oxidation gave a compound of the formula C3H7O2. C with dilute H2SO4 containing Hg2+ ion gave D of formula C3H6O, which with bromine and NaOH gave the sodium salt of C2H4O2. Then A is :
1. CH3CH2CHCl2
2. CH3CCl2CH3
3. CH2ClCH2CH2Cl
4. CH3CHClCH2Cl
Identify the product (A) in following reaction series, (X)(Y)(Z)(A) :
1. CH3CHO
2. CH3CONH2
3. CH3COOH
4. CH3 - CH2-NHOH
In order to accomplish the following conversion, what reagent and conditions would be required?
1. Cold sodium hydroxide
2. Hot conc. sodium hydroxide
3. Potassium tertiary butoxide and heat
4. Hot water
Which of the reagents shown below would accomplish the following transformations?
A B
(a) H3O+ BH3 - THF; H2O2/NaOH
(b) NaOH BH3 - THF; H2O2/NaOH
(c) HBr in ether Hg(OAc)2/H2O; NaBH4
(d) NaNH2 Hg(OAc)2/H2O; NaBH4
Compound and can be differentiated by
(1) H3O⊕, Na
(2) H3O⊕, Tollens' test
(3) H3O⊕, Fehling test
(4) All of these
Give test to differentiate 1,1-dichloroethane and 1, 2-dichloroethane:
1. 2,4-DNP then aq. KOH
2. aq. KOH then 2, 4-DNP
3. NaHSO3
4. Lucas reagent
(1) sp3 to sp2
(2) sp to sp
(3) sp2 to sp
(4) sp to sp3
The reagent used in dehydrohalogenation process is:
(1) alcoholic KOH
(2) NaNH2
(3) C2H5ONa
(4) all of these
The reagent used in dehalogenation process is:
1. KOH alc.
2. Zn dust+ alc.
3. Na
4. KOH(aq)
RCH2OH. This mode of reduction can be effected only by:
1. NaBH4
2. KMnO4
3. LiAIH4
4. All of the above