Which of the following can convert 3-Hexyne into trans-3-Hexene?

1. ${\mathrm{H}}_2$ - Pd/ ${\mathrm{BaSO}}_4$

2. Li-Liq. ${\mathrm{NH}}_3$

3. ${\mathrm{H}}_2$ - Pt ${\mathrm{O}}_2$                

4. ${\mathrm{NaBH}}_4$

Reaction of HBr with propene in the presence of peroxide gives

1. iso-propyl bromide

2. 3-bromo propane

3. allyl bromide

4. n-propyl bromide

An octane number 100 is given to:

1. n-hexane

2. Iso-octane 

3. neo-pentane

4. neo-octane 

In a reaction, 

${\mathrm{CH}}_2={\mathrm{CH}}_2$$\underset{\mathrm{acid}}{\overset{\mathrm{Hypochlorous}}{\to }}$M$\stackrel{\mathrm{R}}{\to }$$\underset{{\mathrm{CH}}_2\mathrm{OH}}{\underset{|}{{\mathrm{CH}}_2\mathrm{OH}}}$

M = molecules, R = reagent. M and R are

1. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{Cl}$ and NaOH

2. ${\mathrm{CH}}_2\mathrm{Cl}.{\mathrm{CH}}_2\mathrm{OH}$ and aq. ${\mathrm{NaHCO}}_3$

3. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{OH}$ and HCl

4.  and heat

Silver acetylide when heated with HCl gives:

1. ${\mathrm{C}}_2{\mathrm{H}}_2$

2. ${\mathrm{H}}_2$

3. ${\mathrm{C}}_2{\mathrm{H}}_4$ 

4. ${\mathrm{C}}_6{\mathrm{H}}_6$

${\mathrm{CH}}_3\mathrm{Cl}\stackrel{\mathrm{Na}}{\to }$Gas A

${\mathrm{CH}}_2\mathrm{COONa}-{\mathrm{CH}}_2\mathrm{COONa}$$\underset{\mathrm{Electrolysis}}{\overset{\mathrm{Kolbe}\text{'}\mathrm{s}}{\to }}$Gas B

${\mathrm{Mg}}_2{\mathrm{C}}_3\stackrel{{\mathrm{H}}_2\mathrm{O}}{\to }$Gas C

Gas (A+B+C) $\underset{{\mathrm{Cu}}_2{\mathrm{Cl}}_2}{\overset{\mathrm{Ammoniacal}}{\to }}$

gas mixture $\underset{\mathrm{Alk}.<mspace\; width="1em"></mspace>{\mathrm{KMnO}}_4}{\overset{\mathrm{Cold}<mspace\; width="1em"></mspace>\mathrm{dil}}{\to }}$ Gas X

Gas X is-

1. Gas A + Gas B                      2. Only Gas B

3. Gas B + Gas C                      4. Only Gas A

Which substrate is appropriate for the preparation of methane and ethane in a single-step process?

1.  H₂C = CH₂

2. CH₃OH

3. CH₃-Br

4. CH₃-CH₂-OH

 
1. \(\mathrm{CH}_3-\mathrm{CH}_3\)
2. \(\mathrm{CH}_2=\mathrm{CH}_2\)
3. \(\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}_2\)
4. None of the above.

Which of the following, when undergoing addition of HBr, will form ONLY a pair of diastereomers?