Consider following compounds and decide as to which of the following statements are true ?

(1) (II) gives no reaction with Na metal, however, 1 mole of (IV) on reaction with Na metal will liberate 22.4 litres of H₂ gas at STP

(2) (I) will give brisk effervescence on addition of NaHCO₃ but will not bring any change in the colour of Br₂ water

(3) (III) Iiberates H2 gas with Na metal, gives white precipitate with Tollen's reagent but does not respond towards lucas reagent or 2, 4–DNP test.

(4) (IV) gives turbidity with anhydrous ZnCI₂

The Prussian blue colour obtained during the test of nitrogen by Lassaigne's test is due to the formation of-

A compound that does not give a positive test in Lassaigne’s test for nitrogen is:

1. Urea

2. Hydrazine

3. Azobenzene

4. Phenylhydrazine

The silver sulphate solution is used to separate:

1. nitrate and bromide

2. nitrate and chlorate

3. bromide and iodide

4. nitrate and nitrite

Soda extract is prepared by-

1. Fusing soda and mixture of hydrocarbons, and then extracted with water

2. Dissolving NaHCO₃ and mixture of hydrocarbons in dil. HCl

3. Boiling Na₂CO₃ and mixture of hydrocarbons in dil. HCl

4. Boiling Na₂CO₃ and mixture of hydrocarbons in distilled water

The Lassaigne's extract is boiled with a concentration HNO₃ while testing for halogens. By doing so it

1. Helps in the precipitation of AgCl

2. Increases the solubility product of AgCl

3. Increases the concentration of NO₃^- ions

4. Decomposes Na₂S and NaCN, if formed.

In the Lassaigne’s test for nitrogen in an organic compound, the Prussian blue colour is obtained due to the formation of-

$1. {\mathrm{Na}}_4\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]$
$2. {\mathrm{Fe}}_4[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6{]}_3$
$3. {\mathrm{Fe}}_2\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]$
$4. {\mathrm{Fe}}_3[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6{]}_4$

Lassaigne's test can detect:

1. Nitrogen, Sulphur, Halogens

2. Nitrogen, Cyanides, Sulphur

3. Sodium, Sulphur, Halogens, Phosphorus

4. Nitrogen, Sulphur, Halogens, Phosphorus

Nitric acid is added to sodium extract before adding silver nitrate for testing halogens because:

1. Nitric acid reduces sulphide

2. Nitric acid decomposes NaCN and Na₂S

3. Nitric acid oxidises the organic compound

4. Nitric acid acts as a dehydrating agent