The octahedral complex will not show geometrical isomerism is :
(A and B are monodentate ligands)

1. [MA4B2]

2. [MA5B]

3. [MA2B4]

4. [MA3B3]

Subtopic:  Isomerism in Coordination Compounds |
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The total number of possible isomers for the complex compound[CuII(NH3)4][PtIICl4] are

1. 5

2. 6

3. 3

4. 4

Subtopic:  Isomerism in Coordination Compounds |
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The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is:

1. [Cr(H2O)4(O2N)]Cl2 2. [Cr(H2O)4Cl2](NO2)
3. [Cr(H2O)4Cl(ONO)]Cl 4. [Cr(H2O)4Cl2(NO2)].H2O
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Which of the following compounds exhibit geometrical isomerism?

1. [Pt(NH3)2Cl2]

2. [Zn(NH3)2Cl2]

3. [Pt(NH3)3Cl

4. All of these

Subtopic:  Isomerism in Coordination Compounds |
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The number of geometrical isomers possible for a square planar complex [Mabcd]±n are

(1) 2

(2) 3

(3) 4

(4) 5

Subtopic:  Isomerism in Coordination Compounds |
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[Cr(en)2Br2]+ can show

(1) Optical isomerism

(2) Geometrical isomerism

(3) Both (1) and (2)

(4) Neither (1) nor (2)

Subtopic:  Isomerism in Coordination Compounds |
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How many hydrate isomers are possible for the molecular formula CoCl3,6H2O?

1. One

2. Two

3. Three

4. Four

Subtopic:  Isomerism in Coordination Compounds |
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The number of ions formed in K4[Fe(CN)6] are

1. 11

2. 5

3. 4

4. 9

Subtopic:  Isomerism in Coordination Compounds |
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Which of the following complex will show geometrical as well as optical isomerism ?

1. [Pt(NH3)2Cl2]

2. [Pt(NH3)Cl3]

3. [Pt(en)2Cl2]

4. [Pt(en)3]4+

Subtopic:  Isomerism in Coordination Compounds |
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Correct increasing order for the wavelengths of absorption in the visible region for the complexes of \(\text{Co}^{3+}\) is:

1. \(\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}\)
2. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}<\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\)
3. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}<\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}\)
4. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}<\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}\)
Subtopic:  Organometallic Complexes & their Uses | Isomerism in Coordination Compounds |
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