The colour of the solution that gets formed by mixing sodium nitroprusside to an alkaline solution of sulfide ions, is-

1. Red 2. Blue
3. Brown 4. Purple

Subtopic:  Quantitative Analysis of Organic Compounds |
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In Kjeldahl's method, the nitrogen present is estimated as-

1. N2 

2. NH3

3. NO2 

4 None of the above

Subtopic:  Quantitative Analysis of Organic Compounds |
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In Duma’s method for estimation of nitrogen, 0.25g of an organic compound gave 40 mL

of nitrogen collected at 300 K temperature and 725 mm pressure. If the aqueous tension

at 300 K is 25 mm, the percentage of nitrogen in the compound is

1. 17.36

2. 18.20..

3. 16.76

4. 15.76

Subtopic:  Quantitative Analysis of Organic Compounds |
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NEET - 2015
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In the Kjeldahl's method for estimation of nitrogen present in a soil sample, ammonia evolved from 0.75 g of sample neutralised 10 mL of 1 M H2SO4. The percentage of nitrogen in the soil is

1. 37.33             2. 45.33

3. 35.33             4. 43.33

 

Subtopic:  Quantitative Analysis of Organic Compounds |
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NEET - 2014
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The Lassaigne's extract is boiled with a concentration HNO3 while testing for halogens. By doing so it:

1. Helps in the precipitation of AgCl.

2. Increases the solubility product of AgCl.

3. Increases the concentration of NO3- ions.

4. Decomposes Na2S and NaCN, if formed.

Subtopic:  Qualitative Analysis of Organic Compounds | Quantitative Analysis of Organic Compounds |
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NEET - 2011
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Ether and benzene can be separated by :-

(1) Filtration

(2) Distillation

(3) Crystallization

(4) Sublimation

Subtopic:  Quantitative Analysis of Organic Compounds |
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0.1688 g organic compound when analyzed by the Dumas method yields 31.7 mL of moist nitrogen measured at 14º C and 758 mm mercury pressure. The % of the nitrogen in the organic compound (Aqueous tension at 14 º C =12 mm) is:

1. 30.9%

2. 10%

3. 40%

4. 21.9 %

Subtopic:  Quantitative Analysis of Organic Compounds |
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0.6 g of an organic compound was Kjeldahlised and NH3 evolved was absorbed into 50 mL of semi-normal solution of H2SO4. The residual acid solution was diluted with distilled water and the volume made up to 150 mL. 20 mL of this diluted solution required 35 mL of N/20 NaOH solution for complete neutralization.

1. 24.2% 

2. 32.4%

3.27.6 %

4. 20.8%

Subtopic:  Quantitative Analysis of Organic Compounds |
Level 3: 35%-60%
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Metallic sodium is fused with organic compounds for testing nitrogen, sulphur, and halogens. The correct reason behind this is:

1. To convert all compounds to their ionic form.
2. Sodium reduces the compounds.
3. Sodium converts all compounds in their covalent form.
4. None of the above.
Subtopic:  Quantitative Analysis of Organic Compounds |
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0.3780 grams of an organic chloro compound gave 0.5740 grams of silver chloride in Carius estimation. % of chlorine present in the compound is -

1. 25% 2. 37.59%
3. 42% 4. 05.70 %
Subtopic:  Quantitative Analysis of Organic Compounds |
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